Secondary Bonding as a Force Dictating Structure and Solid-State Aggregation of the Primary Nitrene Sources (Arylsulfonylimino)iodoarenes (ArINSO2Ar‘)

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Michelle Boucher ◽  
Dainius Macikenas ◽  
Tong Ren ◽  
John D. Protasiewicz
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Ze‐Fan Yao ◽  
Zi‐Yuan Wang ◽  
Hao‐Tian Wu ◽  
Yang Lu ◽  
Qi‐Yi Li ◽  
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Thais Grancha ◽  
Jorge Pasán ◽  
Catalina Ruiz-Pérez ◽  
Laura Cañadillas-Delgado ◽  
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2020 ◽  
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Zi‐Yuan Wang ◽  
Hao‐Tian Wu ◽  
Yang Lu ◽  
Qi‐Yi Li ◽  
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2002 ◽  
Vol 80 (11) ◽  
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Author(s):  
Julio Zukerman-Schpector ◽  
Ionel Haiduc ◽  
Robinson L Camillo ◽  
João V Comasseto ◽  
Rodrigo Luiz Oliveira R. Cunha ◽  
...  

1,1,3-Trichloro-2,4,5,6-tetrahydro-1H-1λ4-benzo[b]tellurophene (a = 8.807(1), b = 14.495(2), c = 9.263(1) Å, β = 110.18(1)°; P21/a, Z= 4, R[F 2 > 2σ(F 2)] = 0.0383), prepared by reacting 1-ethynyl-1-cyclohexanol with tellurium tetrachloride, displays a hexagonal grid structure made of four-membered Te2Cl2 and 12-membered Te6Cl6 rings formed by self-assembly of Cl-Te-Cl rods through Te···Cl secondary bonds into a supramolecular 2D network. The comparison with structurally related compounds reveals that 2D layers can also be formed by similar self-assembly of eight-membered Te4I4 rings alone or in a combination of four-membered Te2I2 with eight-membered Te4I4 rings.Key words: diorganotellurium(IV), supramolecular 2D assembly, self-assembly, secondary bonding.


Author(s):  
Trevor Mathieson ◽  
Annette Schier ◽  
Hubert Schmidbaur

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Ayano Taniguchi ◽  
Daiki Kaji ◽  
Nobuyuki Hara ◽  
Tomomasa Hosoya ◽  
...  

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