Gas Phase Photochemical Synthesis of II/VI Metal Sulfide Films andin SituLuminescence Spectroscopic Identification of Photofragments

1997 ◽  
Vol 119 (16) ◽  
pp. 3838-3839 ◽  
Author(s):  
Jinwoo Cheon ◽  
Jeffrey I. Zink
Keyword(s):  
Gas Phase ◽  
Metal Sulfide ◽  
Photochemical Synthesis ◽  
Spectroscopic Identification

Photochemical synthesis of peroxyacyl nitrates in gas phase via chlorine-aldehyde reaction

1976 ◽  
Vol 10 (1) ◽  
pp. 82-85 ◽  
Author(s):  
Bruce W. Gay ◽  
Richard C. Noonan ◽  
Joseph J. Bufalini ◽  
Philip L. Hanst
Keyword(s):  
Gas Phase ◽  
Photochemical Synthesis ◽  
Peroxyacyl Nitrates

ChemInform Abstract: Gas-Phase Metal Sulfide Cluster Anions.

ChemInform ◽  
2010 ◽  
Vol 27 (25) ◽  
pp. no-no
Author(s):  
K. FISHER ◽  
I. DANCE ◽  
G. WILLETT ◽  
M. YI
Keyword(s):  
Gas Phase ◽  
Metal Sulfide ◽  
Cluster Anions ◽  
Sulfide Cluster

scholarly journals Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity

2018 ◽  
Vol 115 (23) ◽  
pp. 5866-5871 ◽  
Author(s):  
Maximilian Joost ◽  
Matthew Nava ◽  
Wesley J. Transue ◽  
Marie-Aline Martin-Drumel ◽  
Michael C. McCarthy ◽  
...  
Keyword(s):  
Solid State ◽  
Gas Phase ◽  
Transition Metal Complexes ◽  
Organic Molecules ◽  
Rotational Spectroscopy ◽  
Thermal Release ◽  
Molecular Precursor ◽  
Sulfur Monoxide ◽  
Spectroscopic Identification ◽  
Reactive Molecule

Sulfur monoxide (SO) is a highly reactive molecule and thus, eludes bulk isolation. We report here on synthesis and reactivity of a molecular precursor for SO generation, namely 7-sulfinylamino-7-azadibenzonorbornadiene (1). This compound has been shown to fragment readily driven by dinitrogen expulsion and anthracene formation on heating in the solid state and in solution, releasing SO at mild temperatures (<100 °C). The generated SO was detected in the gas phase by MS and rotational spectroscopy. In solution, 1 allows for SO transfer to organic molecules as well as transition metal complexes.

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