Reduction of Inhomogeneous Line Broadening in Two-Dimensional High-Resolution MAS NMR Spectra of Molecules Attached to Swelled Resins in Solid-Phase Synthesis

1997 ◽  
Vol 119 (7) ◽  
pp. 1787-1788 ◽  
Author(s):  
Axel Meissner ◽  
Paw Bloch ◽  
Eberhard Humpfer ◽  
Manfred Spraul ◽  
Ole Winneche Sørensen
Keyword(s):  
High Resolution ◽  
Nmr Spectra ◽  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Mas Nmr ◽  
Two Dimensional ◽  
Line Broadening ◽  
Phase Synthesis ◽  
Inhomogeneous Line Broadening ◽  
Inhomogeneous Line

scholarly journals Hydrate of 2,3:4,5-di-O-isopropylidene-β-D-arabino-hexos-2-ulo-2,6-pyranose as new crystalline reagent in the preparation of Amadori derived peptides

2010 ◽  
Vol 8 (1) ◽  
pp. 28-33 ◽  
Author(s):  
Piotr Stefanowicz ◽  
Joanna Batorska ◽  
Monika Kijewska ◽  
Hubert Bartosz-Bechowski ◽  
Zbigniew Szewczuk ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Nmr Spectroscopy ◽  
High Resolution ◽  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Crystalline Hydrate ◽  
Phase Synthesis ◽  
X Ray ◽  
Independent Molecules ◽  
Stable Reagent

AbstractWe established, that crystalline hydrate of 2,3:4,5-di-O-isopropylidene-β-D-arabino-hexos-2-ulo-2,6-pyranose is a new, convenient and stable reagent for solid phase synthesis of peptide derived Amadori products. The structure of the title compound was studied by X-ray analysis, NMR spectroscopy, and high resolution ESI-MS. The crystal structure indicated the existence of two symmetry-independent molecules that were not connected with hydrogen bonds. A comparison with previously reported 2,3:4,5-di-O-isopropylidene-β-D-fructopyranose revealed, that these two compounds are isostructural.

Solid-phase synthesis and1H and13C high-resolution magic angle spinning NMR of13C-labeled resin-bound saccharides

2004 ◽  
Vol 42 (5) ◽  
pp. 453-458 ◽  
Author(s):  
Nikolaus M. Loening ◽  
Takuya Kanemitsu ◽  
Peter H. Seeberger ◽  
Robert G. Griffin
Keyword(s):  
High Resolution ◽  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Magic Angle Spinning ◽  
Magic Angle ◽  
Phase Synthesis ◽  
Angle Spinning

Solid Phase Synthesis of Coating on the Base under the Electron Beam Surfacing

2013 ◽  
Vol 379 ◽  
pp. 60-65 ◽  
Author(s):  
S.N. Sorokova ◽  
A.G. Knyazeva
Keyword(s):  
Electron Beam ◽  
Solid Phase Synthesis ◽  
Solid Phase ◽  
Two Dimensional ◽  
Dimensional Model ◽  
Phase Synthesis ◽  
Synthesis Conditions ◽  
Two Dimensional Model ◽  
Coating Synthesis

Two-dimensional model of the Ti-Ni coating synthesis in condition of the electron-beam treatment is suggested and investigated. The base is iron. The system of chemical reactions is written according to the phase diagram of Ti-Ni.The results of numerical investigation of the model which illustrate the role of the technology parameters in the conversion regimes are represented. Distribution of temperature and elements concentration and compounds in different time moments for different synthesis conditions are constructed. It is shown that at any process organization the synthesized material becomes chemically heterogeneous.

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