Room Temperature Binding of CO to Cobaltous Porphyrin π Cation Radical:  Spectroscopic Characterization of Mono and Bis CO Complexes with Cobaltic Porphyrin

1996 ◽  
Vol 118 (12) ◽  
pp. 2954-2961 ◽  
Author(s):  
Einhard Schmidt ◽  
Hong Zhang ◽  
Chi K. Chang ◽  
Gerald T. Babcock ◽  
W. Anthony Oertling
Keyword(s):  
Room Temperature ◽  
Cation Radical ◽  
Spectroscopic Characterization

Darstellung, Reaktionen und spektroskopische Charakterisierung von [Os2X8]2-, X = Cl, Br, I, und Kristallstruktur von (PPN)2[Os2I8] · 2 CH2Cl2 / Preparation, Reactions and Spectroscopic Characterization of [Os2X8]2-, X = Cl, Br, I, and Crystal Structure of (PPN)2[Os2I8] · 2 CH2Cl2

1990 ◽  
Vol 45 (10) ◽  
pp. 1416-1424 ◽  
Author(s):  
W. Preetz ◽  
P. Hollmann ◽  
G. Thiele ◽  
H. Hillebrecht
Keyword(s):  
Crystal Structure ◽  
Structure Determination ◽  
Triple Bond ◽  
Room Temperature ◽  
Spectroscopic Characterization ◽  
Spectroscopic Constants ◽  
Monoclinic System ◽  
X Ray ◽  
Fine Structures

The triply bonded octahalogenodiosmate(III) anions [Os2X8]2-, previously known with X = Cl, Br, have now been extended to include the iodide with two staggered OsI4 units. This compound was prepared by treating [Os2Cl8]2- with Nal at room temperature in acetone solution. The structure determination by X-ray diffractometry on single crystals of (PPN)2[Os2I8] · 2 CH2Cl2, reveals crystallization in the monoclinic system, space group P21/c with Z = 4. The Os-Os triple bond is with 2.212(1) Å the longest within the three octahalogenodiosmates(III). The Raman spectra show ν(OsOs) at 285, [Os2Cl8]2-; at 287, [Os2Br8]2- and for the iodo compound at 270.1 cm-1 with up to three overtones. The spectroscopic constants are calculated to be ω1 = 270.9 cm-1; X11 = -0.50 cm-1. The 10 Κ UV-VIS spectra of solid [(n-C4H9)4N]2[Os2X8] exhibit δ-π* transitions with maxima at 723, 690 and 643 nm, superimposed by vibrational fine structures with long progressions of 195, 211 and 183 cm-1 for X = Cl, Br, I, respectively. Oxidation of [Os2X8]2-, X = Cl, Br with the corresponding halogen leads to the cleavage of the Os-Os bond, and the dekahalogenodiosmates(IV), [Os2X10]2-, are formed

Models for peroxidase compound I: generation and spectroscopic characterization of new oxoferryl porphyrin .pi. cation radical species

1992 ◽  
Vol 31 (21) ◽  
pp. 4404-4409 ◽  
Author(s):  
D. Mandon ◽  
R. Weiss ◽  
K. Jayaraj ◽  
A. Gold ◽  
J. Terner ◽  
...  
Keyword(s):  
Cation Radical ◽  
Spectroscopic Characterization ◽  
Compound I ◽  
Radical Species

scholarly journals Synthesis and NMR spectroscopic characterization of Si-substituted 1-silacyclobutene derivatives

2011 ◽  
Vol 9 (1) ◽  
pp. 126-132 ◽  
Author(s):  
Ezzat Khan ◽  
Bernd Wrackmeyer
Keyword(s):  
Magnetic Resonance ◽  
Room Temperature ◽  
Spectroscopic Characterization ◽  
The Other ◽  
Resonance Spectroscopy ◽  
29Si Nmr ◽  
Reaction Conditions ◽  
New Compounds ◽  
Substituted 1

AbstractHydroboration of trialkyn-1-yl(organo)silanes with one equivalent and two equivalents of 9-borabicyclo[3.3.1]nonane, 9-BBN afford dialkyn-1-ylsilanes and alkyn-1-ylsilanes, respectively. The alkyn-1-ylsilane derivatives are stable at room temperature and can be store under dry argon for prolong period of time. These compounds are attractive materials for further rearrangements to afford novel 1-silacyclobutene derivatives bearing Si-alkenyl or Si-alkynyl functionalities. The hydroboration reaction is well controlled by the Si-R1 function, i.e., the starting silanes with R1 = Ph selectively afford hydroboration of one Si-C≡C bond with one equivalent of 9-BBN, leaving the other two functionalities untouched. Under mild reaction conditions (25°C), the starting silanes with R1 = Me lead to mixture containing dialkyn-1-ylsilane, alkyn-1-ylsilane and their respective 1-silacyclobutene derivatives. All new compounds are sensitive towards air and moisture and were studied by multinuclear magnetic resonance spectroscopy (1H, 13C, 11B, 29Si NMR) in solution.

The preparation, X-ray crystal structure, and spectroscopic characterization of pentafluorophenyl-bis(pentafluorophenylthio)sulfonium hexafluoroarsenate, [(C6F5S)2SC6F5][AsF6]

1998 ◽  
Vol 76 (7) ◽  
pp. 1050-1059 ◽  
Author(s):  
Scott Brownridge ◽  
T Stanley Cameron ◽  
Jack Passmore ◽  
Gabriele Schatte ◽  
George W Sutherland
Keyword(s):  
Crystal Structure ◽  
Raman Spectroscopy ◽  
Room Temperature ◽  
Spectroscopic Characterization ◽  
Orthorhombic Space Group ◽  
X Ray ◽  
Cell Dimensions ◽  
Ft Raman Spectroscopy ◽  
Ft Raman

Pentafluorophenyl-bis(pentafluorophenylthio)sulfonium hexafluoroarsenate, [(C6F5S)2SC6F5][AsF6], was prepared by the reaction of (C6F5)2S2 and AsF5 in liquid SO2 at room temperature. The compound has been characterized by single-crystal X-ray and powder diffraction, and IR and FT-Raman spectroscopy. Crystals of [(C6F5S)2SC6F5][AsF6] are orthorhombic, space group P212121 (cell dimensions measured at room temperature in brackets): a = 13.132(3) [13.157(2)] Å, b = 21.477(4) [21.575(3)] Å, c = 8.770(2) [8.775(1)] Å, α = ß = γ = 90.00°; V = 2473.3(9) Å3, Z = 4, temperature = 181 ± 1 K. The structure consists of [AsF6]- anions and [(C6F5S)2SC6F5]+ cations that have a different structure than the related [X2MMMX]+ cations (M = S, Se; X = Cl, Br), which contain a trichalcogen chain with a pronounced chalcogen-chalcogen bond alternation. Ab initio calculations suggest the observed [(C6F5S)2SC6F5]+ geometry is due to steric and solid state effects. Comparison of the Raman spectra of [(C6F5)S2SC6F5][AsF6], [Cl2SSSCl][AsF6], and [(CH3)2ClS3]+ implies that [(CH3)2ClS3]+ has a structure with equal sulfur-sulfur distances, and therefore the structure is likely [(CH3S)2SCl]+ and probably not the previously reported [(CH3)2SSSCl]+.Key words: [R3X3]+ cations, X-ray crystal structure, FT-Raman spectroscopy, [(C6F5S)2SC6F5]+, pentafluorophenyl-bis(pentafluorophenylthio)sulfonium cation, hexafluoroarsenate.

scholarly journals A search for blues brothers: X-ray crystallographic/spectroscopic characterization of the tetraarylbenzidine cation radical as a product of aging of solid magic blue

2016 ◽  
Vol 14 (10) ◽  
pp. 2961-2968 ◽  
Author(s):  
Marat R. Talipov ◽  
Mohammad M. Hossain ◽  
Anitha Boddeda ◽  
Khushabu Thakur ◽  
Rajendra Rathore
Keyword(s):  
Cation Radical ◽  
Spectroscopic Characterization ◽  
Blue Led ◽  
X Ray ◽  
Slow Decomposition

Identification of ‘blues brothers’ formed upon slow decomposition of solid magic blue led to the design of a more robust oxidant named ‘blues cousin’.

scholarly journals Design, Synthesis, Spectroscopic Characterization of New Pyrazole Carbothioamides as Antifungal and Antibacterial Candidates

2021 ◽  
Vol 11 (3) ◽  
pp. 3689-3699
Keyword(s):  
Room Temperature ◽  
Antimicrobial Agents ◽  
Spectroscopic Analysis ◽  
Spectroscopic Characterization ◽  
Efficient Synthesis ◽  
Design Synthesis ◽  
Amberlyst 15 ◽  
New Compounds

In a sustained search for novel antimicrobial agents as weaponry in the war against infectious diseases, resulting in improved survivability for both humans and their domestic animals, the present study demonstrates an efficient synthesis of N,N-dimethylaminophenyl substituted pyrazole carbothioamide derivatives. The synthesis involves (3+2) cycloaddition of chalcones with hydrazinecarbothioamide hydrochloride in the presence of the amberlyst-15 catalyzed at room temperature. The structures of new compounds were characterized by spectroscopic analysis. Furthermore, the synthesized new compounds 5(a-g) were assessed in vitro for their antimicrobial susceptibilities. The results indicate that compounds 5a found potent against tested bacteria species; 5b and 5c show excellent inhibition against the tested fungi and bacteria species. Therefore, these could act as antifungal and antibacterial leads for further investigations.

scholarly journals An efficient synthesis and spectroscopic characterization of Schiff bases containing 9,10-anthracenedione moiety

2013 ◽  
Vol 78 (4) ◽  
pp. 477-482
Author(s):  
Ghulam Fareed ◽  
Ali Versiani ◽  
Nighat Afza ◽  
Nazia Fareed ◽  
Irfan Ali ◽  
...  
Keyword(s):  
Green Chemistry ◽  
Schiff Bases ◽  
1H Nmr ◽  
13C Nmr ◽  
Room Temperature ◽  
Spectroscopic Characterization ◽  
Efficient Synthesis ◽  
Tungstosilicic Acid ◽  
Solvent Free Conditions

A new method has been developed for the synthesis of novel Schiff bases containg anthraquinone moiety using dodeca-Tungstosilicic acid/P2O5 under solvent free conditions at room temperature. The reaction was completed in 1-3 minutes with excellent yields. This method was found to be more efficient, easy and hazardous free for the synthesis of azomethines. The development of these type of methadologies in synthetic chemistry may contribute to green chemistry. The structures of synthesized novel Schiff bases was elucidated using 1H-NMR, 13C-NMR, LCMS, FTIR and CHN analysis.

Synthese, Kristallstruktur und spektroskopische Charakterisierung von Bis(dimethylammonium)hexachlorotitanat [Me2NH2]2[TiCl6]/ Synthesis, Crystal Structure, and Spectroscopic Characterization of Bis(dimethylammonium) Hexachlorotitanate [Me2NH2]2[TiCl6]

2003 ◽  
Vol 58 (5) ◽  
pp. 410-414 ◽  
Author(s):  
Stefan Rannabauer ◽  
Wolfgang Schnick
Keyword(s):  
Room Temperature ◽  
Spectroscopic Characterization ◽  
Local Symmetry ◽  
Structure Type ◽  
Crystalline Powder ◽  
Rutile Structure ◽  
Stoichiometric Reaction ◽  
Ir And Raman ◽  
Yellow Crystalline Powder

By the reaction of (Me3SiNH)2SiClNMe2 with TiCl4 the by-product [Me2NH2]2[TiCl6] was obtained in form of crystals suitable for single-crystal XRD (Pnnm, Z = 2, a = 722.01(3), b = 1428.36(5), c = 703.31(3) pm, T = 200 K, 901 independent reflections, 57 variables, R1 = 0.0636). The product was also synthesized in higher yield by the stoichiometric reaction of two equivalents of [Me2NH2]Cl with TiCl4 in CHCl3 at room temperature as a yellow crystalline powder. Bis(dimethylammonium) hexachlorotitanate is built up from [TiCl6]2- anions forming elongated octahedra and [Me2NH2]+ ions. The [TiCl6]2- ions are connected by the [Me2NH2]+ ions through N-H···Cl hydrogen bridges forming an arrangement which resembles that of an expanded rutile structure type. The elongation of the [TiCl6]2- octahedra was also verified by IR and Raman spectroscopy, confirming a local symmetry reduction from Oh to D4h. The solubility of [Me2NH2]2[TiCl6] in MeNO2 and MeCN was determined by means of 14N-NMR to be about 0.1 mol% and 0.3 mol%, respectively.

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