Gold, Copper, and Platinum Nanoparticles Dispersed on CeOx/TiO2(110) Surfaces: High Water-Gas Shift Activity and the Nature of the Mixed-Metal Oxide at the Nanometer Level

2010 ◽  
Vol 132 (1) ◽  
pp. 356-363 ◽  
Author(s):  
Joon B. Park ◽  
Jesus Graciani ◽  
Jaime Evans ◽  
Dario Stacchiola ◽  
Sanjaya D. Senanayake ◽  
...  
Fuel ◽  
2016 ◽  
Vol 184 ◽  
pp. 382-389 ◽  
Author(s):  
Dalin Li ◽  
Yunbing Cai ◽  
Chongqi Chen ◽  
Xingyi Lin ◽  
Lilong Jiang

2013 ◽  
Vol 2013 ◽  
pp. 1-8
Author(s):  
Klito C. Petallidou ◽  
Kyriaki Polychronopoulou ◽  
Angelos M. Efstathiou

The present work reports on the development of new catalysts for the production of hydrogen via the water-gas shift (WGS) reaction. In particular, the effect of Ce/La atom ratio on the catalytic performance of 0.5 wt% Pt supported on Ce1−xLaxO2−δ (x=0.0,0.2,0.5,0.8,1.0) mixed metal oxides for the WGS reaction was investigated. It was found that the addition of 20 at.% La3+ in CeO2 lattice increased significantly the catalytic activity and stability of 0.5 wt% Pt/Ce0.8La0.2O2−δ solid. More precisely, a lower amount of “carbon” was accumulated on the catalyst surface, whereas surface acidity and basicity studies showed that Ce0.8La0.2O2−δ had the highest concentration of labile oxygen and acid sites, and the lowest concentration of basic sites compared to the other Ce1−xLaxO2−δ mixed metal oxide supports (x=0.2,0.5,0.8).


Author(s):  
Periasamy Anbu ◽  
Subash C.B. Gopinath ◽  
Kandasamy Saravanakumar ◽  
Sekar Vijayakumar ◽  
Santheraleka Ramanathan ◽  
...  

1994 ◽  
Vol 210 (1-2) ◽  
pp. 177-184 ◽  
Author(s):  
K.M. Cruickshank ◽  
F.P. Glasser

2021 ◽  
Vol 4 ◽  
pp. 100085 ◽  
Author(s):  
Karthik Kannan ◽  
D Radhika ◽  
D. Gnanasangeetha ◽  
L. Sivarama Krishna ◽  
K Gurushankar

Catalysts ◽  
2021 ◽  
Vol 11 (3) ◽  
pp. 354
Author(s):  
Khadijah H. Alharbi ◽  
Ali Alsalme ◽  
Ahmed Bader A. Aloumi ◽  
Mohammed Rafiq H. Siddiqui

Oxidation is an important organic transformation, and several catalysts have been reported for this conversion. In this study, we report the synthesis of mixed metal oxide CuxZnyO, which is prepared by a coprecipitation method by varying the molar ratio of Cu and Zn in the catalytic system. The prepared mixed metal oxide CuxZnyO was evaluated for catalytic performance for toluene oxidation. Various parameters of the catalytic evaluation were studied in order to ascertain the optimum condition for the best catalytic performance. The results indicate that aging time, calcination temperature, reaction temperature, and feed rate influence catalytic performance. It was found that the catalyst interfaces apparently enhanced catalytic activity for toluene oxidation. The XRD diffractograms reveal the crystalline nature of the mixed metal oxide formed and also confirm the coexistence of hexagonal and monoclinic crystalline phases. The catalyst prepared by aging for 4 h and calcined at 450 °C was found to be the best for the conversion of toluene to benzaldehyde while the reactor temperature was maintained at 250 °C with toluene fed into the reactor at 0.01 mL/min. The catalyst was active for about 13 h.


Author(s):  
Akash P. Bhat ◽  
Ananda J. Jadhav ◽  
Chandrakant R. Holkar ◽  
Dipak V. Pinjari

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