Palladium-Catalyzed Silylene-1,3-Diene [4 + 1] Cycloaddition with Use of (Aminosilyl)boronic Esters as Synthetic Equivalents of Silylene

2009 ◽  
Vol 131 (46) ◽  
pp. 16624-16625 ◽  
Author(s):  
Toshimichi Ohmura ◽  
Kohei Masuda ◽  
Ichiro Takase ◽  
Michinori Suginome
Keyword(s):  
Boronic Esters ◽  
Palladium Catalyzed

Palladium-catalyzed oxidative homocoupling of pyrazole boronic esters to access versatile bipyrazoles and the flexible metal–organic framework Co(4,4′-bipyrazolate)

2020 ◽  
Vol 56 (8) ◽  
pp. 1195-1198
Author(s):  
Mercedes K. Taylor ◽  
Martin Juhl ◽  
Gul Barg Hadaf ◽  
Dasol Hwang ◽  
Ever Velasquez ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Boronic Esters ◽  
Palladium Catalyzed ◽  
Metal Organic ◽  
Flexible Metal ◽  
Oxidative Homocoupling ◽  
Organic Framework

A facile catalytic protocol achieves the homocoupling of pyrazole boronic esters, enabling access to the structurally-flexible metal–organic framework Co(bpz).

Palladium-Catalyzed Oxidative Hydro-arylation of 1,3-Dienes with Boronic Esters

Synfacts ◽  
2010 ◽  
Vol 2010 (11) ◽  
pp. 1286-1286
Author(s):  
M. Sigman ◽  
L. Liao
Keyword(s):  
Boronic Esters ◽  
Palladium Catalyzed

Efficient synthesis of pyrazine boronic esters via palladium-catalyzed Miyaura borylation

2017 ◽  
Vol 58 (9) ◽  
pp. 839-842 ◽  
Author(s):  
Hongtao Lu ◽  
Shengqiang Wang ◽  
Jingya Li ◽  
Dapeng Zou ◽  
Yusheng Wu ◽  
...  
Keyword(s):  
Efficient Synthesis ◽  
Boronic Esters ◽  
Palladium Catalyzed

Palladium-Catalyzed Reactions of Allylic Boronic Esters with Nucleophiles: Novel Umpolung Reactivity

Synlett ◽  
2015 ◽  
Vol 26 (11) ◽  
pp. 1567-1572 ◽  
Author(s):  
Varinder Aggarwal ◽  
Phillip Unsworth ◽  
Lorenz Löffler ◽  
Adam Noble
Keyword(s):  
Boronic Esters ◽  
Palladium Catalyzed ◽  
Catalyzed Reactions

scholarly journals The Synthesis of Biarylmonophosphonates via Palladium-Catalyzed Phosphonation, Iridium-Catalyzed C-H Borylation, Palladium-Catalyzed Suzuki–Miyaura Cross-Coupling

2021 ◽  
Author(s):  
Simon Doherty ◽  
Julian G. Knight ◽  
Tina S. T. Tran ◽  
Hussam Y. Alharbi ◽  
Daniel O. Perry
Keyword(s):  
Cross Coupling ◽  
Statistical Mixture ◽  
Boronic Ester ◽  
Synthetic Procedure ◽  
Boronic Esters ◽  
Palladium Catalyzed ◽  
Nucleophilic Reagents ◽  
Sole Product

Abstract The iridium-catalyzed C-H borylation of diethyl phenylphosphonate results in nonselective mono and bisborylation to afford a near statistical mixture of 3-, 3,5- and 4-boryl substituted aryl phosphonates whereas 3-substituted aryl phosphonates undergo highly regioselective C-H borylation to afford the corresponding meta-phosphonate substituted arylboronic esters as the sole product; the resulting boronic esters were used as nucleophilic reagents in a subsequent palladium-catalyzed Suzuki–Miyaura cross-coupling to generate a range of biarylmonophosphonates. Gratifyingly, the Suzuki–Miyaura cross-coupling can be conducted without purifying the boronic ester which greatly simplifies the synthetic procedure. Graphical Abstract

Aerobic Alcohol Oxidation Coupled to Palladium-Catalyzed Alkene Hydroarylation with Boronic Esters

2008 ◽  
Vol 120 (17) ◽  
pp. 3263-3266 ◽  
Author(s):  
Yasumasa Iwai ◽  
Keith M. Gligorich ◽  
Matthew S. Sigman
Keyword(s):  
Alcohol Oxidation ◽  
Boronic Esters ◽  
Palladium Catalyzed
Sign in / Sign up

Export Citation Format

Share Document