Palladium-catalyzed oxidative homocoupling of pyrazole boronic esters to access versatile bipyrazoles and the flexible metal–organic framework Co(4,4′-bipyrazolate)

2020 ◽  
Vol 56 (8) ◽  
pp. 1195-1198
Author(s):  
Mercedes K. Taylor ◽  
Martin Juhl ◽  
Gul Barg Hadaf ◽  
Dasol Hwang ◽  
Ever Velasquez ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Boronic Esters ◽  
Palladium Catalyzed ◽  
Metal Organic ◽  
Flexible Metal ◽  
Oxidative Homocoupling ◽  
Organic Framework

A facile catalytic protocol achieves the homocoupling of pyrazole boronic esters, enabling access to the structurally-flexible metal–organic framework Co(bpz).

scholarly journals Corrigendum: Tuning Gate‐Opening of a Flexible Metal–Organic Framework for Ternary Gas Sieving Separation

2021 ◽  
Vol 60 (8) ◽  
pp. 3850-3850
Author(s):  
Qiubing Dong ◽  
Xin Zhang ◽  
Shuang Liu ◽  
Rui‐Biao Lin ◽  
Yanan Guo ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Gate Opening ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

scholarly journals Exceptional adsorption-induced cluster and network deformation in the flexible metal–organic framework DUT-8(Ni) observed by in situ X-ray diffraction and EXAFS

2015 ◽  
Vol 17 (26) ◽  
pp. 17471-17479 ◽  
Author(s):  
Volodymyr Bon ◽  
Nicole Klein ◽  
Irena Senkovska ◽  
Andreas Heerwig ◽  
Jürgen Getzschmann ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
X Ray ◽  
Gate Opening ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

The “gate opening” mechanism in flexible MOF Ni2(2,6-ndc)2dabco was elucidated in detail.

scholarly journals Particle size effects in the kinetic trapping of a structurally-locked form of a flexible MOF

CrystEngComm ◽  
2016 ◽  
Vol 18 (22) ◽  
pp. 4172-4179 ◽  
Author(s):  
Oliver M. Linder-Patton ◽  
Witold M. Bloch ◽  
Campbell J. Coghlan ◽  
Kenji Sumida ◽  
Susumu Kitagawa ◽  
...  
Keyword(s):  
Particle Size ◽  
Size Effects ◽  
Metal Organic Framework ◽  
Particle Size Effects ◽  
Metal Organic ◽  
Flexible Metal ◽  
Kinetic Trapping ◽  
2D To 3D ◽  
Organic Framework

Controlling the particle size of a flexible metal–organic framework demonstrates that a 2D to 3D transformation gives a kinetically-trapped, structurally-locked form.

Flexible Metal-Organic Framework-Based Mixed-Matrix Membranes: A New Platform for H2 S Sensors

Small ◽  
2018 ◽  
Vol 14 (37) ◽  
pp. 1801563 ◽  
Author(s):  
Xin Zhang ◽  
Qi Zhang ◽  
Dan Yue ◽  
Jun Zhang ◽  
Jintong Wang ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Mixed Matrix Membranes ◽  
Mixed Matrix ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework ◽  
Matrix Membranes

Size-Control and Surface Modification of Flexible Metal-Organic Framework MIL-53(Fe) by Polyethyleneglycol for 5- Fluorouracil Anticancer Drug Delivery

2019 ◽  
Vol 4 (8) ◽  
pp. 2333-2338 ◽  
Author(s):  
Hoai Phuong Nguyen Thi ◽  
Ha Duc Ninh ◽  
Chinh Van Tran ◽  
Bac Thanh Le ◽  
Sheshanath V. Bhosale ◽  
...  
Keyword(s):  
Drug Delivery ◽  
Surface Modification ◽  
Anticancer Drug ◽  
Metal Organic Framework ◽  
Size Control ◽  
Anticancer Drug Delivery ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

Stepwise Evolution of Molecular Nanoaggregates Inside the Pores of a Highly Flexible Metal–Organic Framework

2019 ◽  
Vol 131 (48) ◽  
pp. 17503-17511 ◽  
Author(s):  
Davide Balestri ◽  
Paolo P. Mazzeo ◽  
Claudia Carraro ◽  
Nicola Demitri ◽  
Paolo Pelagatti ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Metal Organic ◽  
Flexible Metal ◽  
Stepwise Evolution ◽  
Organic Framework

Solvent exchange in a metal–organic framework single crystal monitored by dynamicin situX-ray diffraction

2017 ◽  
Vol 73 (4) ◽  
pp. 669-674 ◽  
Author(s):  
Jordan M. Cox ◽  
Ian M. Walton ◽  
Gage Bateman ◽  
Cassidy A. Benson ◽  
Travis Mitchell ◽  
...  
Keyword(s):  
Rational Design ◽  
Metal Organic Framework ◽  
X Ray Diffraction ◽  
Guest Molecules ◽  
Time Resolved ◽  
Ethanol Solvate ◽  
Significant Step ◽  
Metal Organic ◽  
Flexible Metal ◽  
Organic Framework

Understanding the processes by which porous solid-state materials adsorb and release guest molecules would represent a significant step towards developing rational design principles for functional porous materials. To elucidate the process of liquid exchange in these materials, dynamicin situX-ray diffraction techniques have been developed which utilize liquid-phase chemical stimuli. Using these time-resolved diffraction techniques, the ethanol solvation process in a flexible metal–organic framework [Co(AIP)(bpy)0.5(H2O)]·2H2O was examined. The measurements provide important insight into the nature of the chemical transformation in this system including the presence of a previously unreported neat ethanol solvate structure.

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