Monomeric and Oligomeric Amine−Borane σ-Complexes of Rhodium. Intermediates in the Catalytic Dehydrogenation of Amine−Boranes

2009 ◽  
Vol 131 (42) ◽  
pp. 15440-15456 ◽  
Author(s):  
Thomas M. Douglas ◽  
Adrian B. Chaplin ◽  
Andrew S. Weller ◽  
Xinzheng Yang ◽  
Michael B. Hall
Keyword(s):  
Catalytic Dehydrogenation ◽  
Amine Boranes

scholarly journals B-Methylated Amine-Boranes: Substituent Redistribution, Catalytic Dehydrogenation, and Facile Metal-Free Hydrogen Transfer Reactions

2015 ◽  
Vol 54 (22) ◽  
pp. 10878-10889 ◽  
Author(s):  
Naomi E. Stubbs ◽  
André Schäfer ◽  
Alasdair P. M. Robertson ◽  
Erin M. Leitao ◽  
Titel Jurca ◽  
...  
Keyword(s):  
Hydrogen Transfer ◽  
Transfer Reactions ◽  
Catalytic Dehydrogenation ◽  
Metal Free ◽  
Free Hydrogen ◽  
Amine Boranes ◽  
Hydrogen Transfer Reactions

Amine-Borane σ-Complexes of Rhodium. Relevance to the Catalytic Dehydrogenation of Amine-Boranes

2008 ◽  
Vol 130 (44) ◽  
pp. 14432-14433 ◽  
Author(s):  
Thomas M. Douglas ◽  
Adrian B. Chaplin ◽  
Andrew S. Weller
Keyword(s):  
Catalytic Dehydrogenation ◽  
Amine Boranes

scholarly journals Variable coordination modes and catalytic dehydrogenation of B-phenyl amine–boranes

2016 ◽  
Vol 45 (14) ◽  
pp. 6183-6195 ◽  
Author(s):  
Amit Kumar ◽  
Isobel K. Priest ◽  
Thomas N. Hooper ◽  
Andrew S. Weller
Keyword(s):  
Binding Mode ◽  
Catalytic Dehydrogenation ◽  
Coordination Modes ◽  
Bite Angle ◽  
Amine Boranes ◽  
Variable Coordination

The binding mode ofB-aryl substituted amine–boranes at {Rh(bisphoshine)}+fragments can manipulated by variation of the P–Rh–P bite-angle.

scholarly journals Catalytic Dehydrogenation of Amine‐Boranes using Geminal Phosphino‐Boranes

2020 ◽  
Vol 646 (13) ◽  
pp. 586-592 ◽  
Author(s):  
Devin H. A. Boom ◽  
Ewoud J. J. de Boed ◽  
Emmanuel Nicolas ◽  
Martin Nieger ◽  
Andreas W. Ehlers ◽  
...  
Keyword(s):  
Catalytic Dehydrogenation ◽  
Amine Boranes

Stoichiometric reactions and catalytic dehydrogenations of amine–boranes with calcium aryloxide

2019 ◽  
Vol 55 (62) ◽  
pp. 9152-9155 ◽  
Author(s):  
Xizhou Zheng ◽  
Jiasu Huang ◽  
Yingming Yao ◽  
Xin Xu
Keyword(s):  
Active Species ◽  
Catalytic Dehydrogenation ◽  
Dehydrogenation Reactions ◽  
Amine Boranes

A calcium aryloxide complex reacts with amine–boranes to give unprecedented amine–borane coordinated complexes through Ca⋯H interactions, which serve as active species for catalytic dehydrogenation reactions.

Catalytic Dehydrogenation of (Di)Amine-Boranes with a Geometrically Constrained Phosphine-Borane Lewis Pair

ACS Catalysis ◽  
2018 ◽  
Vol 8 (5) ◽  
pp. 4459-4464 ◽  
Author(s):  
Maxime Boudjelel ◽  
E. Daiann Sosa Carrizo ◽  
Sonia Mallet−Ladeira ◽  
Stéphane Massou ◽  
Karinne Miqueu ◽  
...  
Keyword(s):  
Catalytic Dehydrogenation ◽  
Geometrically Constrained ◽  
Amine Boranes
Sign in / Sign up

Export Citation Format

Share Document