Dioxygen Activation by Mononuclear Nonheme Iron(II) Complexes Generates Iron−Oxygen Intermediates in the Presence of an NADH Analogue and Proton

2009 ◽  
Vol 131 (39) ◽  
pp. 13910-13911 ◽  
Author(s):  
Seungwoo Hong ◽  
Yong-Min Lee ◽  
Woonsup Shin ◽  
Shunichi Fukuzumi ◽  
Wonwoo Nam
Keyword(s):  
Nonheme Iron ◽  
Dioxygen Activation ◽  
Oxygen Intermediates

Dioxygen Activation at Mononuclear Nonheme Iron Active Sites:  Enzymes, Models, and Intermediates

2004 ◽  
Vol 104 (2) ◽  
pp. 939-986 ◽  
Author(s):  
Miquel Costas ◽  
Mark P. Mehn ◽  
Michael P. Jensen ◽  
Lawrence Que
Keyword(s):  
Active Sites ◽  
Nonheme Iron ◽  
Dioxygen Activation ◽  
Iron Active Sites

Dioxygen Activation at Mononuclear Nonheme Iron Active Sites: Enzymes, Models, and Intermediates

ChemInform ◽  
2004 ◽  
Vol 35 (21) ◽  
Author(s):  
Miquel Costas ◽  
Mark P. Mehn ◽  
Michael P. Jensen ◽  
Lawrence Jr. Que
Keyword(s):  
Active Sites ◽  
Nonheme Iron ◽  
Dioxygen Activation ◽  
Iron Active Sites

scholarly journals Proton- and Reductant-Assisted Dioxygen Activation by a Nonheme Iron(II) Complex to Form an Oxoiron(IV) Intermediate

2008 ◽  
Vol 47 (37) ◽  
pp. 7064-7067 ◽  
Author(s):  
Aurore Thibon ◽  
Jason England ◽  
Marlène Martinho ◽  
Victor G. Young ◽  
Jonathan R. Frisch ◽  
...  
Keyword(s):  
Nonheme Iron ◽  
Dioxygen Activation

Dioxygen Activation and Catalytic Aerobic Oxidation by a Mononuclear Nonheme Iron(II) Complex

2005 ◽  
Vol 127 (12) ◽  
pp. 4178-4179 ◽  
Author(s):  
Sun Ok Kim ◽  
Chivukula V. Sastri ◽  
Mi Sook Seo ◽  
Jinheung Kim ◽  
Wonwoo Nam
Keyword(s):  
Aerobic Oxidation ◽  
Nonheme Iron ◽  
Dioxygen Activation

Dioxygen activation and two consecutive oxidative decarboxylations of phenylpyruvate by nonheme iron(ii) complexes: functional models of hydroxymandelate synthase (HMS) and CloR

2015 ◽  
Vol 51 (36) ◽  
pp. 7681-7684 ◽  
Author(s):  
Debobrata Sheet ◽  
Shrabanti Bhattacharya ◽  
Tapan Kanti Paine
Keyword(s):  
Benzoic Acid ◽  
Mandelic Acid ◽  
Nonheme Iron ◽  
Dioxygen Activation ◽  
Tridentate Ligands ◽  
Functional Models

Iron(ii)–phenylpyruvate complexes of facial tridentate ligands react with dioxygen to undergo two consecutive oxidative decarboxylations to form benzoic acid via mandelic acid.

Dioxygen activation chemistry by synthetic mononuclear nonheme iron, copper and chromium complexes

2017 ◽  
Vol 334 ◽  
pp. 25-42 ◽  
Author(s):  
Seungwoo Hong ◽  
Yong-Min Lee ◽  
Kallol Ray ◽  
Wonwoo Nam
Keyword(s):  
Nonheme Iron ◽  
Dioxygen Activation ◽  
Chromium Complexes ◽  
Iron Copper

Formation of cobalt-oxygen intermediates by dioxygen activation at a mononuclear nonheme cobalt(II) center

2021 ◽  
Author(s):  
Deesha D. Malik ◽  
Anirban Chandra ◽  
Mi Sook Seo ◽  
Yong-Min Lee ◽  
Erik R. Farquhar ◽  
...  
Keyword(s):  
Hydrogen Atom ◽  
Dioxygen Activation ◽  
Oxygen Intermediates

A mononuclear nonheme cobalt(II) complex, [(TMG3tren)CoII(OTf)](OTf) (1), activates dioxygen in the presence of hydrogen atom donor substrates, such as tetrahydrofuran and cyclohexene, resulting in the generation of a cobalt(II)-alkylperoxide intermediate...

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