Optimized Acetylene/Carbon Dioxide Sorption in a Dynamic Porous Crystal

2009 ◽  
Vol 131 (15) ◽  
pp. 5516-5521 ◽  
Author(s):  
Jie-Peng Zhang ◽  
Xiao-Ming Chen
Keyword(s):  
Carbon Dioxide ◽  
Carbon Dioxide Sorption ◽  
Porous Crystal ◽  
Acetylene Carbon

Carbon dioxide sorption and melting behaviour of mPEG-alkyne

2021 ◽  
Vol 171 ◽  
pp. 105182
Author(s):  
S. López ◽  
M.J. Ramos ◽  
J.M. García-Vargas ◽  
M.T. García ◽  
J.F. Rodríguez ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Melting Behaviour ◽  
Carbon Dioxide Sorption

Calorimetric probes of carbon dioxide sorption in bisphenol-A based polymers

Polymer ◽  
1997 ◽  
Vol 38 (23) ◽  
pp. 5807-5813 ◽  
Author(s):  
Tapan Banerjee ◽  
G. Glenn Lipscomb
Keyword(s):  
Carbon Dioxide ◽  
Bisphenol A ◽  
Carbon Dioxide Sorption

C3H2O2 Acetylene - carbon dioxide (1/1)

2005 ◽  
pp. 1-1
Author(s):  
G. Graner ◽  
E. Hirota ◽  
T. Iijima ◽  
K. Kuchitsu ◽  
D. A. Ramsay ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Acetylene Carbon

scholarly journals Dilation kinetics of glassy, aromatic polyimides induced by carbon dioxide sorption

1995 ◽  
Vol 33 (9) ◽  
pp. 1371-1384 ◽  
Author(s):  
M. Wessling ◽  
I. Huisman ◽  
Th. v. d. Boomgaard ◽  
C. A. Smolders
Keyword(s):  
Carbon Dioxide ◽  
Aromatic Polyimides ◽  
Carbon Dioxide Sorption ◽  
Kinetics Of

Carbon dioxide sorption on polish ortholignite coal in low and elevated pressure

2013 ◽  
Vol 3-4 ◽  
pp. 44-48 ◽  
Author(s):  
Paweł Baran ◽  
Janusz Cygankiewicz ◽  
Katarzyna Zarębska
Keyword(s):  
Carbon Dioxide ◽  
Elevated Pressure ◽  
Carbon Dioxide Sorption

scholarly journals Ethylenediamine loading into a manganese-based metal–organic framework enhances water stability and carbon dioxide uptake of the framework

2020 ◽  
Vol 7 (3) ◽  
pp. 191934 ◽  
Author(s):  
Aisha Asghar ◽  
Naseem Iqbal ◽  
Leena Aftab ◽  
Tayyaba Noor ◽  
Benson M. Kariuki ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Metal Organic Framework ◽  
Carbon Dioxide Uptake ◽  
Coordination Sites ◽  
Carbon Dioxide Sorption ◽  
Metal Organic ◽  
Amine Groups ◽  
Thermogravimetric Studies ◽  
Original Metal ◽  
Very High

Metal–organic frameworks (MOFs) based on 2,5-dihydroxyterepthalic acid (DOBDC) as the linker show very high CO 2 uptake capacities at low to moderate CO 2 pressures; however, these MOFs often require expensive solvent for synthesis and are difficult to regenerate. We have synthesized a Mn-DOBDC MOF and modified it to introduce amine groups into the structure by functionalizing its metal coordination sites with ethylenediamine (EDA). Repeat framework synthesis was then also successfully performed using recycled dimethylformamide (DMF) solvent. Characterization by elemental analysis, FTIR and thermogravimetric studies suggest that EDA molecules are successfully substituting the original metal-bound DMF. This modification not only enhances the material's carbon dioxide sorption capacity, increasing stability to repeated CO 2 sorption cycles, but also improves the framework's stability to moisture. Moreover, this is one of the first amine-modified MOFs that can demonstrably be synthesized using recycled solvent, potentially reducing the future costs of production at larger scales.

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