Detection of the Short-Lived Cation Radical Intermediate in the Electrochemical Oxidation of N,N-Dimethylaniline by Scanning Electrochemical Microscopy

2014 ◽  
Vol 136 (52) ◽  
pp. 18163-18169 ◽  
Author(s):  
Fahe Cao ◽  
Jiyeon Kim ◽  
Allen J. Bard
Keyword(s):  
Electrochemical Oxidation ◽  
Cation Radical ◽  
Scanning Electrochemical Microscopy ◽  
Radical Intermediate ◽  
Electrochemical Microscopy

scholarly journals Use of Amperometric and Potentiometric Probes in Scanning Electrochemical Microscopy for the Spatially-Resolved Monitoring of Severe Localized Corrosion Sites on Aluminum Alloy 2098-T351

Sensors ◽  
2021 ◽  
Vol 21 (4) ◽  
pp. 1132 ◽  
Author(s):  
Rejane M. P. da Silva ◽  
Javier Izquierdo ◽  
Mariana X. Milagre ◽  
Abenchara M. Betancor-Abreu ◽  
Isolda Costa ◽  
...  
Keyword(s):  
Scanning Electrochemical Microscopy ◽  
Oxygen Depletion ◽  
Localized Corrosion ◽  
Alloy Surface ◽  
Al Alloy ◽  
Spatially Resolved ◽  
Lower Oxygen ◽  
Local Ph ◽  
Electrochemical Microscopy

Amperometric and potentiometric probes were employed for the detection and characterization of reactive sites on the 2098-T351 Al-alloy (AA2098-T351) using scanning electrochemical microscopy (SECM). Firstly, the probe of concept was performed on a model Mg-Al galvanic pair system using SECM in the amperometric and potentiometric operation modes, in order to address the responsiveness of the probes for the characterization of this galvanic pair system. Next, these sensing probes were employed to characterize the 2098-T351 alloy surface immersed in a saline aqueous solution at ambient temperature. The distribution of reactive sites and the local pH changes associated with severe localized corrosion (SLC) on the alloy surface were imaged and subsequently studied. Higher hydrogen evolution, lower oxygen depletion and acidification occurred at the SLC sites developed on the 2098-T351 Al-alloy.

Local electrochemical activity of transition metal dichalcogenides and their heterojunctions on 3D-printed nanocarbon surfaces

Nanoscale ◽  
2021 ◽  
Author(s):  
Katarina A. Novčić ◽  
Christian Iffelsberger ◽  
Siowwoon Ng ◽  
Martin Pumera
Keyword(s):  
Transition Metal ◽  
Electrochemical Performance ◽  
Transition Metal Dichalcogenides ◽  
Scanning Electrochemical Microscopy ◽  
Electrochemical Activity ◽  
Thermally Activated ◽  
Metal Dichalcogenides ◽  
3D Printed ◽  
Electrochemical Microscopy

MoS2 and WS2 and their heterojunctions are used to modify thermally activated 3D-printed nanocarbon structures. Herein, the local electrochemical performance for HER of the modified structures is demonstrated by scanning electrochemical microscopy.

scholarly journals Simultaneous Intelligent Imaging of Nanoscale Reactivity and Topography by Scanning Electrochemical Microscopy

2021 ◽  
Author(s):  
Dylan T. Jantz ◽  
Ryan J. Balla ◽  
Siao-Han Huang ◽  
Niraja Kurapati ◽  
Shigeru Amemiya ◽  
...  
Keyword(s):  
Scanning Electrochemical Microscopy ◽  
Electrochemical Microscopy

scholarly journals Biological Scanning Electrochemical Microscopy and Its Application to Live Cell Studies

2011 ◽  
Vol 83 (5) ◽  
pp. 1485-1492 ◽  
Author(s):  
Isabelle Beaulieu ◽  
Sabine Kuss ◽  
Janine Mauzeroll ◽  
Matthias Geissler
Keyword(s):  
Scanning Electrochemical Microscopy ◽  
Live Cell ◽  
Electrochemical Microscopy
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