From 1D Chain to 3D Network: A New Family of Inorganic–Organic Hybrid Semiconductors MO3(L)x (M = Mo, W; L = Organic Linker) Built on Perovskite-like Structure Modules

2013 ◽  
Vol 135 (46) ◽  
pp. 17401-17407 ◽  
Author(s):  
Xiao Zhang ◽  
Mehdi Hejazi ◽  
Suraj J. Thiagarajan ◽  
William R. Woerner ◽  
Debasis Banerjee ◽  
...  
Keyword(s):  
Organic Hybrid ◽  
New Family ◽  
3D Network ◽  
1D Chain ◽  
Hybrid Semiconductors ◽  
Organic Linker

Inorganic–organic hybrid high-dimensional polyoxotantalates and their structural transformations triggered by water

2019 ◽  
Vol 55 (78) ◽  
pp. 11735-11738 ◽  
Author(s):  
Zhong Li ◽  
Jing Zhang ◽  
Li-Dan Lin ◽  
Jin-Hua Liu ◽  
Xin-Xiong Li ◽  
...  
Keyword(s):  
Structural Transformations ◽  
High Dimensional ◽  
Organic Hybrid ◽  
New Family

In this work, novel dimeric polyoxotantalate (POTa) clusters {Cu(en)(Ta6O19)}2/{Cu(enMe)(Ta6O19)}2 were introduced as SBUs to construct a new family of extended POTa materials, including the first two 3D POTa frameworks and two 2D POTa layers.

Syntheses, structures, and magnetic properties of two unique Cu(ii)-based coordination polymers involving a crystal-to-crystal structural transformation from a 1D chain to a 3D network

2017 ◽  
Vol 46 (48) ◽  
pp. 17025-17031 ◽  
Author(s):  
Xu-Feng Yang ◽  
Min Liu ◽  
Hai-Bin Zhu ◽  
Cheng Hang ◽  
Yue Zhao
Keyword(s):  
Magnetic Properties ◽  
Structural Transformation ◽  
Coordination Polymers ◽  
Network Structure ◽  
Chain Structure ◽  
3D Network ◽  
1D Chain ◽  
Crystal Structural

Promoted by the DMF solvent, the 1D chain structure of 1 can be irreversibly transformed into the 3D sod network structure of 2 in a crystal-to-crystal fashion, which is accompanied by a drastic magnetic change.

Nanostructured crystals: An unprecedented class of hybrid semiconductors exhibiting structure-induced quantum confinement effect and systematically tunable properties

2017 ◽  
Author(s):  
Jing Li ◽  
Xiao-Ying Huang
Keyword(s):  
Quantum Confinement ◽  
Quantum Confinement Effect ◽  
Three Dimensional ◽  
Hybrid Nanostructures ◽  
Confinement Effect ◽  
Design And Synthesis ◽  
Organic Hybrid ◽  
Expansion Behavior ◽  
Dimensional Network ◽  
Hybrid Semiconductors

This article describes the structure-induced quantum confinement effect in nanostructured crystals, a unique class of hybrid semiconductors that incorporate organic and inorganic components into a single-crystal lattice via covalent (coordinative) bonds to form extended one-, two- and three-dimensional network structures. These structures are comprised of subnanometer-sized II-VI semiconductor segments (inorganic component) and amine molecules (organic component) arranged into perfectly ordered arrays. The article first provides an overview of II-VI and III-V semiconductors, II-VI colloidal quantum dots, inorganic-organic hybrid materials before discussing the design and synthesis of I-VI-based inorganic-organic hybrid nanostructures. It also considers the crystal structures, quantum confinement effect, bandgaps, and optical properties, thermal properties, thermal expansion behavior of nanostructured crystals.

From 1D chain to 3D network: A theoretical study on TiO2 low dimensional structures

2015 ◽  
Vol 142 (22) ◽  
pp. 224305 ◽  
Author(s):  
Ling-ju Guo ◽  
Zhi Zeng ◽  
Tao He
Keyword(s):  
Theoretical Study ◽  
3D Network ◽  
1D Chain ◽  
Low Dimensional

Synthesis, structural, thermal and optical studies of inorganic-organic hybrid semiconductors, R-PbI4

2013 ◽  
Vol 113 (8) ◽  
pp. 083523 ◽  
Author(s):  
K. Pradeesh ◽  
K. Nageswara Rao ◽  
G. Vijaya Prakash
Keyword(s):  
Optical Studies ◽  
Organic Hybrid ◽  
Hybrid Semiconductors

New Family of Lanthanide-Based Inorganic–Organic Hybrid Frameworks: Ln2(OH)4[O3S(CH2)nSO3]·2H2O (Ln = La, Ce, Pr, Nd, Sm; n = 3, 4) and Their Derivatives

2013 ◽  
Vol 52 (4) ◽  
pp. 1755-1761 ◽  
Author(s):  
Jianbo Liang ◽  
Renzhi Ma ◽  
Yasuo Ebina ◽  
Fengxia Geng ◽  
Takayoshi Sasaki
Keyword(s):  
Organic Hybrid ◽  
New Family

ChemInform Abstract: A Novel Inorganic-Organic Hybrid 1D Chain Built by Double Banana-Shaped Tungstoarsenates {Co(Hen)[Co6As3W24O94 (H2O)2]}228-.

ChemInform ◽  
2011 ◽  
Vol 42 (51) ◽  
pp. no-no
Author(s):  
Pengtao Ma ◽  
Lijuan Chen ◽  
Junwei Zhao ◽  
Wei Wang ◽  
Jingping Wang ◽  
...  
Keyword(s):  
Organic Hybrid ◽  
1D Chain

scholarly journals Three cobalt-based coordination polymers with tripodal carboxylate and imidazole-containing ligands: syntheses, structures, properties and DFT studies

RSC Advances ◽  
2019 ◽  
Vol 9 (66) ◽  
pp. 38902-38911 ◽  
Author(s):  
Long Tang ◽  
Huan-Huan Wang ◽  
Yu-Hao Fu ◽  
Yi-Tong Wang ◽  
JiJiang Wang ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Magnetic Behavior ◽  
Fluorescence Properties ◽  
Carboxylate Ligand ◽  
Dft Studies ◽  
3D Network ◽  
1D Chain ◽  
2D To 3D

The tripodal carboxylate ligand can be employed in Co(ii) salt/imidazole-containing ligand systems to generate 1D chain, 2D layer, and 2D to 3D network, and the fluorescence properties of 1–3 and magnetic behavior of 1 and 2 have been investigated.

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