scholarly journals Molecular Origin of Rapid versus Slow Intramolecular Electron Transfer in the Catalytic Cycle of the Multicopper Oxidases

2013 ◽  
Vol 135 (33) ◽  
pp. 12212-12215 ◽  
Author(s):  
David E. Heppner ◽  
Christian H. Kjaergaard ◽  
Edward I. Solomon
Keyword(s):  
Electron Transfer ◽  
Catalytic Cycle ◽  
Intramolecular Electron Transfer ◽  
Multicopper Oxidases ◽  
Molecular Origin

Tetracopper Assembly Complexes Comprised of One Dimetallic Core and Two Monometallic Auxiliaries:  Intramolecular Electron-Transfer Relevant to Multicopper Oxidases

1999 ◽  
Vol 38 (8) ◽  
pp. 1825-1830 ◽  
Author(s):  
Sayaka Yamanaka ◽  
Hisashi Ōkawa ◽  
Ken-ichiro Motoda ◽  
Masami Yonemura ◽  
David E. Fenton ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Intramolecular Electron Transfer ◽  
Multicopper Oxidases

Intramolecular Electron Transfer Mediated by a Tetrathiafulvalene Bridge in a Purely Organic Mixed-Valence System

2003 ◽  
Vol 42 (24) ◽  
pp. 2765-2768 ◽  
Author(s):  
Nicolas Gautier ◽  
Frédéric Dumur ◽  
Vega Lloveras ◽  
José Vidal-Gancedo ◽  
Jaume Veciana ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Mixed Valence ◽  
Intramolecular Electron Transfer

scholarly journals Solvent-induced on/off switching of intramolecular electron transfer in a cyanide-bridged trigonal bipyramidal complex

2016 ◽  
Vol 45 (43) ◽  
pp. 17104-17107 ◽  
Author(s):  
Rong-Jia Wei ◽  
Ryohei Nakahara ◽  
Jamie M. Cameron ◽  
Graham N. Newton ◽  
Takuya Shiga ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Spin Transition ◽  
Intramolecular Electron Transfer ◽  
Thermally Induced ◽  
Trigonal Bipyramidal ◽  
Transition Behaviour

A cyanide-bridged trigonal bipyramidal [Co3Fe2] cluster shows solvent-driven reversible on/off switching of its thermally induced electron-transfer-coupled spin transition behaviour.

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