scholarly journals Mechanistic Study of Stepwise Methylisocyanide Coupling and C–H Activation Mediated by a Low-Valent Main Group Molecule

2013 ◽  
Vol 135 (16) ◽  
pp. 6257-6261 ◽  
Author(s):  
Zachary D. Brown ◽  
Petra Vasko ◽  
Jeremy D. Erickson ◽  
James C. Fettinger ◽  
Heikki M. Tuononen ◽  
...  
Keyword(s):  
Main Group ◽  
Mechanistic Study ◽  
Low Valent

scholarly journals Ligand coordination modulates reductive elimination from aluminium(iii)

2016 ◽  
Vol 45 (35) ◽  
pp. 13695-13699 ◽  
Author(s):  
Stephanie J. Urwin ◽  
David M. Rogers ◽  
Gary S. Nichol ◽  
Michael J. Cowley
Keyword(s):  
Oxidative Addition ◽  
Reductive Elimination ◽  
Main Group ◽  
Mechanistic Study ◽  
Ligand Effects ◽  
Major Class ◽  
Reverse Process ◽  
Ligand Coordination ◽  
Low Valent

Oxidative addition to low-valent main-group centres is a major class of reactivity for these species. Here, we present a mechanistic study of the much rarer reverse process – reductive elimination – in Al(iii) systems, and unravel ligand effects in this process.

Main-group metal complexes of α-diimine ligands: structure, bonding and reactivity

2021 ◽  
Author(s):  
Rong Zhang ◽  
Yanchao Wang ◽  
Yanxia Zhao ◽  
Carl Redshaw ◽  
Igor L. Fedushkin ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Small Molecule ◽  
Main Group ◽  
Group Metal ◽  
Diimine Ligands ◽  
Main Group Metal ◽  
Metal Metal ◽  
Low Valent

The use of dad (and bian) ligands in the stabilization of main-group complexes, in particular metal–metal-bonded compounds, as well as the small molecule reactivity of these (low-valent) metal complexes, is summarized.

scholarly journals Breaking Carbon–Fluorine Bonds with Main Group Nucleophiles

Synlett ◽  
2019 ◽  
Vol 30 (20) ◽  
pp. 2233-2246 ◽  
Author(s):  
Greg Coates ◽  
Feriel Rekhroukh ◽  
Mark R. Crimmin
Keyword(s):  
Main Group ◽  
Main Group Compounds ◽  
Low Valent

In this Account we describe a series of new reactions that we, and others, have reported that involve the transformation of C–F bonds into C–Mg, C–Al, C–Si, C–Fe and C–Zn bonds. We focus on the use of highly reactive main group nucleophiles and discuss aspects of reaction scope, selectivity and mechanism.1 Introduction1.1 The Fluorocarbon Industry and Sustainability1.2 Production of Fluorocarbons1.3 Properties of Fluorocarbons1.4 Our Work2 Results and Discussion2.1 Low-Valent Main Group Compounds2.1.1 Reactions with Fluoroarenes2.1.2 Reactions with Fluoroalkanes2.1.3 Reactions with Fluoroalkenes2.2 Main Group Nucleophiles (M1–M2)2.2.1 Reactions of M1–M2 Nucleophiles with Fluoroarenes2.2.2 Reactions of M1–M2 Nucleophiles with Fluoroalkanes2.2.3 Reactions of M1–M2 Nucleophiles with Fluoroalkenes3 Summary and Perspective

Theoretical Evidence for the Utilization of Low-Valent Main-Group Complexes as Rare-Synthon Equivalents

2017 ◽  
Vol 23 (71) ◽  
pp. 17908-17914
Author(s):  
Zsolt Benedek ◽  
Balázs Orbán ◽  
Tibor Szilvási
Keyword(s):  
Main Group ◽  
Low Valent ◽  
Theoretical Evidence
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