ChemInform Abstract: Cages with Low-Valent Elements of Main Group IV Heavy Congeners of Isocyanide (Alkylisocyanide) and Carbon Monoxide

1986 ◽  
Vol 17 (37) ◽  
Author(s):  
M. VEITH
Keyword(s):  
Carbon Monoxide ◽  
Main Group ◽  
Group Iv ◽  
Low Valent

Main-group metal complexes of α-diimine ligands: structure, bonding and reactivity

2021 ◽  
Author(s):  
Rong Zhang ◽  
Yanchao Wang ◽  
Yanxia Zhao ◽  
Carl Redshaw ◽  
Igor L. Fedushkin ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Small Molecule ◽  
Main Group ◽  
Group Metal ◽  
Diimine Ligands ◽  
Main Group Metal ◽  
Metal Metal ◽  
Low Valent

The use of dad (and bian) ligands in the stabilization of main-group complexes, in particular metal–metal-bonded compounds, as well as the small molecule reactivity of these (low-valent) metal complexes, is summarized.

Hyperconjugation in phenyl and benzyl derivatives of the main group IV elements

1988 ◽  
Vol 344 (1) ◽  
pp. 49-60 ◽  
Author(s):  
A.N. Egorochkin ◽  
G.A. Razuvaev ◽  
M.A. Lopatin
Keyword(s):  
Main Group ◽  
Group Iv ◽  
Group Iv Elements ◽  
Derivatives Of

scholarly journals Breaking Carbon–Fluorine Bonds with Main Group Nucleophiles

Synlett ◽  
2019 ◽  
Vol 30 (20) ◽  
pp. 2233-2246 ◽  
Author(s):  
Greg Coates ◽  
Feriel Rekhroukh ◽  
Mark R. Crimmin
Keyword(s):  
Main Group ◽  
Main Group Compounds ◽  
Low Valent

In this Account we describe a series of new reactions that we, and others, have reported that involve the transformation of C–F bonds into C–Mg, C–Al, C–Si, C–Fe and C–Zn bonds. We focus on the use of highly reactive main group nucleophiles and discuss aspects of reaction scope, selectivity and mechanism.1 Introduction1.1 The Fluorocarbon Industry and Sustainability1.2 Production of Fluorocarbons1.3 Properties of Fluorocarbons1.4 Our Work2 Results and Discussion2.1 Low-Valent Main Group Compounds2.1.1 Reactions with Fluoroarenes2.1.2 Reactions with Fluoroalkanes2.1.3 Reactions with Fluoroalkenes2.2 Main Group Nucleophiles (M1–M2)2.2.1 Reactions of M1–M2 Nucleophiles with Fluoroarenes2.2.2 Reactions of M1–M2 Nucleophiles with Fluoroalkanes2.2.3 Reactions of M1–M2 Nucleophiles with Fluoroalkenes3 Summary and Perspective

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