Multiple-Site Concerted Proton–Electron Transfer Reactions of Hydrogen-Bonded Phenols Are Nonadiabatic and Well Described by Semiclassical Marcus Theory

Joel N. Schrauben; Mauricio Cattaneo; Thomas C. Day; Adam L. Tenderholt; James M. Mayer

doi:10.1021/ja305668h

Multiple-Site Concerted Proton–Electron Transfer Reactions of Hydrogen-Bonded Phenols Are Nonadiabatic and Well Described by Semiclassical Marcus Theory

Journal of the American Chemical Society ◽

10.1021/ja305668h ◽

2012 ◽

Vol 134 (40) ◽

pp. 16635-16645 ◽

Cited By ~ 60

Author(s):

Joel N. Schrauben ◽

Mauricio Cattaneo ◽

Thomas C. Day ◽

Adam L. Tenderholt ◽

James M. Mayer

Keyword(s):

Electron Transfer ◽

Marcus Theory ◽

Transfer Reactions ◽

Multiple Site ◽

Electron Transfer Reactions ◽

Hydrogen Bonded

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ChemInform Abstract: Electron-Transfer Reactions: Reactions of Indoles with Nitrosonium Ion. Application of the Marcus Theory. Crystal Structures of 1-Methyl-3,4-, -3,5- and -3,6-dinitro-2-phenylindoles.

ChemInform ◽

10.1002/chin.199331105 ◽

2010 ◽

Vol 24 (31) ◽

pp. no-no

Author(s):

L. EBERSON ◽

E. GIORGINI ◽

L. GRECI ◽

G. TOSI ◽

C. RIZZOLI ◽

...

Keyword(s):

Electron Transfer ◽

Crystal Structures ◽

Marcus Theory ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Nitrosonium Ion

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Electron Transfer Reactions in Organic Chemistry. V. Examination of Postulated Electron Transfer Processes Involving Anionic and Carbanionic Nucleophiles with the Aid of the Marcus Theory.

Acta Chemica Scandinavica ◽

10.3891/acta.chem.scand.38b-0439 ◽

1984 ◽

Vol 38b ◽

pp. 439-459 ◽

Cited By ~ 65

Author(s):

Lennart Eberson ◽

Rolf Carlson ◽

Kjell Undheim ◽

Lars Mörch ◽

Torbjörn Norin

Keyword(s):

Organic Chemistry ◽

Electron Transfer ◽

Marcus Theory ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Transfer Processes ◽

Electron Transfer Processes

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Additions and Corrections - Kinetics of the Electron Transfer Reactions of Azaviolene Radical Ions. 2. Correlation with the Marcus Theory. The Question of Concerted Acid-Base Catalysis.

Journal of the American Chemical Society ◽

10.1021/ja00457a605 ◽

1977 ◽

Vol 99 (15) ◽

pp. 5228-5228

Author(s):

Claude Bernasconi ◽

Hsien-Chang Wang

Keyword(s):

Electron Transfer ◽

Marcus Theory ◽

Base Catalysis ◽

Transfer Reactions ◽

Radical Ions ◽

Acid Base ◽

Electron Transfer Reactions ◽

Kinetics Of

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Activation parameters for homogeneous outer-sphere electron-transfer reactions. Comparisons between self-exchange and cross reactions using Marcus' theory

Inorganic Chemistry ◽

10.1021/ic50209a023 ◽

1980 ◽

Vol 19 (7) ◽

pp. 1936-1945 ◽

Cited By ~ 74

Author(s):

Michael J. Weaver ◽

Edmund L. Yee

Keyword(s):

Electron Transfer ◽

Activation Parameters ◽

Outer Sphere ◽

Marcus Theory ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Cross Reactions ◽

Outer Sphere Electron Transfer

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ChemInform Abstract: ELECTRON-TRANSFER REACTIONS IN ORGANIC CHEMISTRY. II. AN ANALYSIS OF ALKYL HALIDE REDUCTION BY ELECTRON-TRANSFER REAGENTS ON THE BASIS OF THE MARCUS THEORY

Chemischer Informationsdienst ◽

10.1002/chin.198303110 ◽

1983 ◽

Vol 14 (3) ◽

Author(s):

L. EBERSON

Keyword(s):

Organic Chemistry ◽

Electron Transfer ◽

Alkyl Halide ◽

Marcus Theory ◽

Transfer Reactions ◽

Electron Transfer Reactions

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ESR-Spectroscopic Investigation of the Homogeneous Electron Transfer Reactions between Substituted p-Phenylenediamines and Quinonediimines, and the Validity of Marcus' Theory. I. Measurements at 293 K

Berichte der Bunsengesellschaft für physikalische Chemie ◽

10.1002/bbpc.19840880403 ◽

1984 ◽

Vol 88 (4) ◽

pp. 325-334 ◽

Cited By ~ 61

Author(s):

Günter Grampp ◽

Walther Jaenicke

Keyword(s):

Electron Transfer ◽

Spectroscopic Investigation ◽

Marcus Theory ◽

Transfer Reactions ◽

Electron Transfer Reactions

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Experimental Validation of Marcus Theory for Outer-Sphere Heterogeneous Electron-Transfer Reactions: The Oxidation of Substituted 1,4-Phenylenediamines

ChemPhysChem ◽

10.1002/cphc.200400128 ◽

2004 ◽

Vol 5 (8) ◽

pp. 1234-1240 ◽

Cited By ~ 18

Author(s):

Antony D. Clegg ◽

Neil V. Rees ◽

Oleksiy V. Klymenko ◽

Barry A. Coles ◽

Richard G. Compton

Keyword(s):

Electron Transfer ◽

Experimental Validation ◽

Outer Sphere ◽

Marcus Theory ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Heterogeneous Electron Transfer

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Kinetics of the electron-transfer reactions of azaviolene radical ions. 2. Correlation with the Marcus theory. The question of concerted acid-base catalysis

Journal of the American Chemical Society ◽

10.1021/ja00449a031 ◽

1977 ◽

Vol 99 (7) ◽

pp. 2214-2221 ◽

Cited By ~ 6

Author(s):

Claude F. Bernasconi ◽

Hsien-Chang Wang

Keyword(s):

Electron Transfer ◽

Marcus Theory ◽

Base Catalysis ◽

Transfer Reactions ◽

Radical Ions ◽

Acid Base ◽

Electron Transfer Reactions ◽

Kinetics Of

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Are the current theories of electron transfer applicable to reactions in ionic liquids? An ESR-study on the TCNE/TCNE−˙ couple

Physical Chemistry Chemical Physics ◽

10.1039/c6cp01750a ◽

2016 ◽

Vol 18 (21) ◽

pp. 14442-14448 ◽

Cited By ~ 6

Author(s):

B. Y. Mladenova ◽

D. R. Kattnig ◽

B. Sudy ◽

P. Choto ◽

G. Grampp

Keyword(s):

Electron Transfer ◽

Ionic Liquids ◽

Marcus Theory ◽

Transfer Reactions ◽

Activation Barriers ◽

Electron Transfer Reactions ◽

Solvent Properties

Electron transfer reactions in ionic liquids are profoundly affected by solvent properties. The activation barriers cannot be generally accounted for by Marcus' theory.

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Rate constants and activation parameters for outer-sphere electron-transfer reactions and comparisons with the predictions of Marcus theory

Journal of the American Chemical Society ◽

10.1021/ja00459a014 ◽

1977 ◽

Vol 99 (17) ◽

pp. 5615-5623 ◽

Cited By ~ 122

Author(s):

Mei Chou ◽

Carol Creutz ◽

Norman Sutin

Keyword(s):

Electron Transfer ◽

Rate Constants ◽

Activation Parameters ◽

Outer Sphere ◽

Marcus Theory ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Outer Sphere Electron Transfer

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