Experimental Validation of Marcus Theory for Outer-Sphere Heterogeneous Electron-Transfer Reactions: The Oxidation of Substituted 1,4-Phenylenediamines

Antony D. Clegg; Neil V. Rees; Oleksiy V. Klymenko; Barry A. Coles; Richard G. Compton

doi:10.1002/cphc.200400128

Experimental Validation of Marcus Theory for Outer-Sphere Heterogeneous Electron-Transfer Reactions: The Oxidation of Substituted 1,4-Phenylenediamines

ChemPhysChem ◽

10.1002/cphc.200400128 ◽

2004 ◽

Vol 5 (8) ◽

pp. 1234-1240 ◽

Cited By ~ 18

Author(s):

Antony D. Clegg ◽

Neil V. Rees ◽

Oleksiy V. Klymenko ◽

Barry A. Coles ◽

Richard G. Compton

Keyword(s):

Electron Transfer ◽

Experimental Validation ◽

Outer Sphere ◽

Marcus Theory ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Heterogeneous Electron Transfer

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Marcus theory of outer-sphere heterogeneous electron transfer reactions: High precision steady-state measurements of the standard electrochemical rate constant for ferrocene derivatives in alkyl cyanide solvents

Journal of Electroanalytical Chemistry ◽

10.1016/j.jelechem.2005.03.013 ◽

2005 ◽

Vol 580 (1) ◽

pp. 78-86 ◽

Cited By ~ 50

Author(s):

Antony D. Clegg ◽

Neil V. Rees ◽

Oleksiy V. Klymenko ◽

Barry A. Coles ◽

Richard G. Compton

Keyword(s):

Electron Transfer ◽

Steady State ◽

High Precision ◽

Rate Constant ◽

Outer Sphere ◽

Marcus Theory ◽

Transfer Reactions ◽

Ferrocene Derivatives ◽

Electron Transfer Reactions ◽

Heterogeneous Electron Transfer

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Marcus Theory of Outer-Sphere Heterogeneous Electron Transfer Reactions: Dependence of the Standard Electrochemical Rate Constant on the Hydrodynamic Radius from High Precision Measurements of the Oxidation of Anthracene and Its Derivatives in Nonaqueous Solvents Using the High-Speed Channel Electrode

Journal of the American Chemical Society ◽

10.1021/ja040014v ◽

2004 ◽

Vol 126 (19) ◽

pp. 6185-6192 ◽

Cited By ~ 33

Author(s):

Antony D. Clegg ◽

Neil V. Rees ◽

Oleksiy V. Klymenko ◽

Barry A. Coles ◽

Richard G. Compton

Keyword(s):

Electron Transfer ◽

High Precision ◽

High Speed ◽

Hydrodynamic Radius ◽

Outer Sphere ◽

Marcus Theory ◽

Transfer Reactions ◽

Precision Measurements ◽

Heterogeneous Electron Transfer ◽

Channel Electrode

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Activation parameters for homogeneous outer-sphere electron-transfer reactions. Comparisons between self-exchange and cross reactions using Marcus' theory

Inorganic Chemistry ◽

10.1021/ic50209a023 ◽

1980 ◽

Vol 19 (7) ◽

pp. 1936-1945 ◽

Cited By ~ 74

Author(s):

Michael J. Weaver ◽

Edmund L. Yee

Keyword(s):

Electron Transfer ◽

Activation Parameters ◽

Outer Sphere ◽

Marcus Theory ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Cross Reactions ◽

Outer Sphere Electron Transfer

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Rate constants and activation parameters for outer-sphere electron-transfer reactions and comparisons with the predictions of Marcus theory

Journal of the American Chemical Society ◽

10.1021/ja00459a014 ◽

1977 ◽

Vol 99 (17) ◽

pp. 5615-5623 ◽

Cited By ~ 122

Author(s):

Mei Chou ◽

Carol Creutz ◽

Norman Sutin

Keyword(s):

Electron Transfer ◽

Rate Constants ◽

Activation Parameters ◽

Outer Sphere ◽

Marcus Theory ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Outer Sphere Electron Transfer

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ChemInform Abstract: RATE CONSTANTS AND ACTIVATION PARAMETERS FOR OUTER-SPHERE ELECTRON-TRANSFER REACTIONS AND COMPARISONS WITH THE PREDICTIONS OF MARCUS THEORY

Chemischer Informationsdienst ◽

10.1002/chin.197748344 ◽

1977 ◽

Vol 8 (48) ◽

pp. no-no

Author(s):

M. CHOU ◽

C. CREUTZ ◽

N. SUTIN

Keyword(s):

Electron Transfer ◽

Rate Constants ◽

Activation Parameters ◽

Outer Sphere ◽

Marcus Theory ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Outer Sphere Electron Transfer

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The Analysis of Solvent Effects on the Kinetics of Simple Heterogeneous Electron Transfer Reactions

10.21236/ada210078 ◽

1988 ◽

Author(s):

W. R. Fawcett ◽

Jr Foss ◽

C. A.

Keyword(s):

Electron Transfer ◽

Solvent Effects ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Heterogeneous Electron Transfer ◽

Kinetics Of

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Estimation of the Outer Sphere Contribution to the Activation Parameters for Homogeneous Electron Transfer Reactions Using the Mean Spherical Approximation

10.21236/ada243217 ◽

1991 ◽

Author(s):

W. R. Fawcett ◽

L. Blum

Keyword(s):

Electron Transfer ◽

Activation Parameters ◽

Outer Sphere ◽

Transfer Reactions ◽

Spherical Approximation ◽

Mean Spherical Approximation ◽

Electron Transfer Reactions ◽

The Mean

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Mechanistic information from the effect of pressure on outer-sphere electron-transfer reactions involving the reduction of cobalt(III) by iron(II) complexes in aqueous solution

Inorganic Chemistry ◽

10.1021/ic00231a004 ◽

1986 ◽

Vol 25 (11) ◽

pp. 1743-1747 ◽

Cited By ~ 23

Author(s):

I. Krack ◽

R. Van Eldik

Keyword(s):

Aqueous Solution ◽

Electron Transfer ◽

Outer Sphere ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Effect Of Pressure ◽

Outer Sphere Electron Transfer

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Mechanism of the elementary act and calculation of the rate constants of some outer-sphere electron transfer reactions of transition metal complexes

Theoretical and Experimental Chemistry ◽

10.1007/bf00519844 ◽

1983 ◽

Vol 18 (3) ◽

pp. 249-255

Author(s):

V. M. Berdnikov ◽

G. A. Bogdanchikov

Keyword(s):

Electron Transfer ◽

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Rate Constants ◽

Outer Sphere ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Outer Sphere Electron Transfer

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Observation of temperature independent heterogeneous electron transfer reactions in the inverted Marcus region

Chemical Physics ◽

10.1016/0301-0104(93)80257-a ◽

1993 ◽

Vol 176 (2-3) ◽

pp. 493-500 ◽

Cited By ~ 130

Author(s):

Jacques E. Moser ◽

Michael Grätzel

Keyword(s):

Electron Transfer ◽

Transfer Reactions ◽

Electron Transfer Reactions ◽

Heterogeneous Electron Transfer

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