1,1′-Azobis-1,2,3-triazole: A High-Nitrogen Compound with Stable N8Structure and Photochromism

2010 ◽  
Vol 132 (35) ◽  
pp. 12172-12173 ◽  
Author(s):  
Yu-Chuan Li ◽  
Cai Qi ◽  
Sheng-Hua Li ◽  
Hui-Juan Zhang ◽  
Cheng-Hui Sun ◽  
...  
2006 ◽  
Vol 31 (3) ◽  
pp. 163-168 ◽  
Author(s):  
Bryce C. Tappan ◽  
Arif N. Ali ◽  
Steven F. Son ◽  
Thomas B. Brill

Molecules ◽  
2020 ◽  
Vol 25 (2) ◽  
pp. 314
Author(s):  
Rafał Lewczuk ◽  
Maria Książek ◽  
Katarzyna Gańczyk-Specjalska ◽  
Katarzyna Cieślak

A high-nitrogen compound, 2,2′-azobis(1H-imidazole-4,5-dicarbonitrile) (TCAD), was synthesized from commercially available 2-amino-1H-imidazole-4,5-dicarbonitrile. It was characterized with infrared and nuclear magnetic resonance spectroscopy. Its structure was determined by single crystal X-ray diffraction. The crystal of TCAD tetrahydrate is monoclinic, with space group P21/c with crystal parameters of a = 10.2935(2) Å, b = 7.36760(10) Å, c = 20.1447(4) Å, V = 1500.27(5) Å3, Z = 4, and F(000) = 688. Computational methods were used in order to fully optimize the molecular structure, calculate the electrostatic potential of an isolated molecule, and to compute thermodynamic parameters. TCAD has very high thermal stability with temperature of decomposition at 369 °C. Kinetics of thermal decomposition of this compound were studied and apparent energy of activation as well as the maximum safe temperature of technological process were determined.


Polyhedron ◽  
2016 ◽  
Vol 117 ◽  
pp. 445-452 ◽  
Author(s):  
Feipeng Lu ◽  
Engyu Wang ◽  
Jinglun Huang ◽  
Ming Huang ◽  
Fude Nie ◽  
...  

2007 ◽  
Vol 149 (2) ◽  
pp. 527-531 ◽  
Author(s):  
Michael P. Cronin ◽  
Anthony I. Day ◽  
Lynne Wallace

2015 ◽  
Vol 604 ◽  
pp. 106-114 ◽  
Author(s):  
Qi-Long Yan ◽  
Tomáš Musil ◽  
Svatopluk Zeman ◽  
Robert Matyáš ◽  
Xiao-Bing Shi ◽  
...  

2017 ◽  
Vol 129 (16) ◽  
pp. 4583-4585 ◽  
Author(s):  
Chong Zhang ◽  
Chen Yang ◽  
Bingcheng Hu ◽  
Chuanming Yu ◽  
Zhansheng Zheng ◽  
...  

2007 ◽  
Vol 142 (1-2) ◽  
pp. 550-554 ◽  
Author(s):  
Bao-Juan Jiao ◽  
San-Ping Chen ◽  
Feng-Qi Zhao ◽  
Rong-Zu Hu ◽  
Sheng-Li Gao

2017 ◽  
Vol 56 (16) ◽  
pp. 4512-4514 ◽  
Author(s):  
Chong Zhang ◽  
Chen Yang ◽  
Bingcheng Hu ◽  
Chuanming Yu ◽  
Zhansheng Zheng ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document