Decomposition and Ignition of the High-Nitrogen Compound Triaminoguanidinium Azotetrazolate (TAGzT)

2006 ◽  
Vol 31 (3) ◽  
pp. 163-168 ◽  
Author(s):  
Bryce C. Tappan ◽  
Arif N. Ali ◽  
Steven F. Son ◽  
Thomas B. Brill
Keyword(s):  
Nitrogen Compound ◽  
High Nitrogen ◽  
Triaminoguanidinium Azotetrazolate

scholarly journals Structure and Thermal Properties of 2,2′-Azobis(1H-Imidazole-4,5-Dicarbonitrile)—A Promising Starting Material for a Novel Group of Energetic Compounds

Molecules ◽  
2020 ◽  
Vol 25 (2) ◽  
pp. 314
Author(s):  
Rafał Lewczuk ◽  
Maria Książek ◽  
Katarzyna Gańczyk-Specjalska ◽  
Katarzyna Cieślak
Keyword(s):  
Molecular Structure ◽  
Nitrogen Compound ◽  
High Thermal Stability ◽  
Resonance Spectroscopy ◽  
Energetic Compounds ◽  
X Ray Diffraction ◽  
High Nitrogen ◽  
X Ray ◽  
Kinetics Of ◽  
Very High

A high-nitrogen compound, 2,2′-azobis(1H-imidazole-4,5-dicarbonitrile) (TCAD), was synthesized from commercially available 2-amino-1H-imidazole-4,5-dicarbonitrile. It was characterized with infrared and nuclear magnetic resonance spectroscopy. Its structure was determined by single crystal X-ray diffraction. The crystal of TCAD tetrahydrate is monoclinic, with space group P21/c with crystal parameters of a = 10.2935(2) Å, b = 7.36760(10) Å, c = 20.1447(4) Å, V = 1500.27(5) Å3, Z = 4, and F(000) = 688. Computational methods were used in order to fully optimize the molecular structure, calculate the electrostatic potential of an isolated molecule, and to compute thermodynamic parameters. TCAD has very high thermal stability with temperature of decomposition at 369 °C. Kinetics of thermal decomposition of this compound were studied and apparent energy of activation as well as the maximum safe temperature of technological process were determined.

The synthesis, property and reduction of high-nitrogen compound 3,3′,5,5′-tetraazido-4,4′-bis(1,2,4-triazole)

Polyhedron ◽  
2016 ◽  
Vol 117 ◽  
pp. 445-452 ◽  
Author(s):  
Feipeng Lu ◽  
Engyu Wang ◽  
Jinglun Huang ◽  
Ming Huang ◽  
Fude Nie ◽  
...  
Keyword(s):  
Nitrogen Compound ◽  
High Nitrogen

Electrochemical remediation produces a new high-nitrogen compound from NTO wastewaters

2007 ◽  
Vol 149 (2) ◽  
pp. 527-531 ◽  
Author(s):  
Michael P. Cronin ◽  
Anthony I. Day ◽  
Lynne Wallace
Keyword(s):  
Nitrogen Compound ◽  
High Nitrogen ◽  
Electrochemical Remediation

Preparation, morphologies and thermal behavior of high nitrogen compound 2-amino-4,6-diazido-s-triazine and its derivatives

2015 ◽  
Vol 604 ◽  
pp. 106-114 ◽  
Author(s):  
Qi-Long Yan ◽  
Tomáš Musil ◽  
Svatopluk Zeman ◽  
Robert Matyáš ◽  
Xiao-Bing Shi ◽  
...  
Keyword(s):  
Thermal Behavior ◽  
Nitrogen Compound ◽  
High Nitrogen

A Symmetric Co(N5 )2 (H2 O)4 ⋅4 H2 O High-Nitrogen Compound Formed by Cobalt(II) Cation Trapping of a Cyclo-N5 − Anion

2017 ◽  
Vol 129 (16) ◽  
pp. 4583-4585 ◽  
Author(s):  
Chong Zhang ◽  
Chen Yang ◽  
Bingcheng Hu ◽  
Chuanming Yu ◽  
Zhansheng Zheng ◽  
...  
Keyword(s):  
Nitrogen Compound ◽  
High Nitrogen

A new high-nitrogen compound [Mn(ATZ)(H2O)4]·2H2O: Synthesis and characterization

2007 ◽  
Vol 142 (1-2) ◽  
pp. 550-554 ◽  
Author(s):  
Bao-Juan Jiao ◽  
San-Ping Chen ◽  
Feng-Qi Zhao ◽  
Rong-Zu Hu ◽  
Sheng-Li Gao
Keyword(s):  
Nitrogen Compound ◽  
Synthesis And Characterization ◽  
High Nitrogen

1,1′-Azobis-1,2,3-triazole: A High-Nitrogen Compound with Stable N8Structure and Photochromism

2010 ◽  
Vol 132 (35) ◽  
pp. 12172-12173 ◽  
Author(s):  
Yu-Chuan Li ◽  
Cai Qi ◽  
Sheng-Hua Li ◽  
Hui-Juan Zhang ◽  
Cheng-Hui Sun ◽  
...  
Keyword(s):  
Nitrogen Compound ◽  
High Nitrogen

A Symmetric Co(N5 )2 (H2 O)4 ⋅4 H2 O High-Nitrogen Compound Formed by Cobalt(II) Cation Trapping of a Cyclo-N5 − Anion

2017 ◽  
Vol 56 (16) ◽  
pp. 4512-4514 ◽  
Author(s):  
Chong Zhang ◽  
Chen Yang ◽  
Bingcheng Hu ◽  
Chuanming Yu ◽  
Zhansheng Zheng ◽  
...  
Keyword(s):  
Nitrogen Compound ◽  
High Nitrogen
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