Oxidation Catalysis of Nb(salan) Complexes: Asymmetric Epoxidation of Allylic Alcohols Using Aqueous Hydrogen Peroxide as an Oxidant

2010 ◽  
Vol 132 (16) ◽  
pp. 5886-5895 ◽  
Author(s):  
Hiromichi Egami ◽  
Takuya Oguma ◽  
Tsutomu Katsuki
Keyword(s):  
Hydrogen Peroxide ◽  
Oxidation Catalysis ◽  
Asymmetric Epoxidation ◽  
Allylic Alcohols ◽  
Aqueous Hydrogen Peroxide

scholarly journals Metal-Organic Frameworks in Oxidation Catalysis with Hydrogen Peroxide

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 283
Author(s):  
Oxana Kholdeeva ◽  
Nataliya Maksimchuk
Keyword(s):  
Hydrogen Peroxide ◽  
Liquid Phase ◽  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Short Review ◽  
Catalytic Performance ◽  
Oxidation Catalysis ◽  
Catalyst Stability ◽  
Aqueous Hydrogen Peroxide ◽  
Metal Organic

In recent years, metal–organic frameworks (MOFs) have received increasing attention as selective oxidation catalysts and supports for their construction. In this short review paper, we survey recent findings concerning use of MOFs in heterogeneous liquid-phase selective oxidation catalysis with the green oxidant–aqueous hydrogen peroxide. MOFs having outstanding thermal and chemical stability, such as Cr(III)-based MIL-101, Ti(IV)-based MIL-125, Zr(IV)-based UiO-66(67), Zn(II)-based ZIF-8, and some others, will be in the main focus of this work. The effects of the metal nature and MOF structure on catalytic activity and oxidation selectivity are analyzed and the mechanisms of hydrogen peroxide activation are discussed. In some cases, we also make an attempt to analyze relationships between liquid-phase adsorption properties of MOFs and peculiarities of their catalytic performance. Attempts of using MOFs as supports for construction of single-site catalysts through their modification with heterometals will be also addressed in relation to the use of such catalysts for activation of H2O2. Special attention is given to the critical issues of catalyst stability and reusability. The scope and limitations of MOF catalysts in H2O2-based selective oxidation are discussed.

scholarly journals A bottom up approach towards artificial oxygenases by combining iron coordination complexes and peptides

2017 ◽  
Vol 8 (5) ◽  
pp. 3660-3667 ◽  
Author(s):  
Olaf Cussó ◽  
Michael W. Giuliano ◽  
Xavi Ribas ◽  
Scott J. Miller ◽  
Miquel Costas
Keyword(s):  
Hydrogen Peroxide ◽  
Coordination Complexes ◽  
Asymmetric Epoxidation ◽  
Coordination Complex ◽  
High Yield ◽  
Aqueous Hydrogen Peroxide ◽  
Bottom Up ◽  
Iron Coordination

The combination of peptides and a chiral iron coordination complex catalyzes high yield highly asymmetric epoxidation with aqueous hydrogen peroxide.

Titanium–Salan-Catalyzed Asymmetric Epoxidation with Aqueous Hydrogen Peroxide as the Oxidant

2006 ◽  
Vol 118 (21) ◽  
pp. 3558-3560 ◽  
Author(s):  
Yuji Sawada ◽  
Kazuhiro Matsumoto ◽  
Shoichi Kondo ◽  
Hisayuki Watanabe ◽  
Tomoyuki Ozawa ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Asymmetric Epoxidation ◽  
Aqueous Hydrogen Peroxide

Asymmetric Epoxidation with Aqueous Hydrogen Peroxide as the Oxidant

Synfacts ◽  
2006 ◽  
Vol 2006 (8) ◽  
pp. 0804-0804
Author(s):  
T. Katsuki ◽  
Y. Sawada ◽  
K. Matsumoto ◽  
S. Kondo ◽  
H. Watanabe ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Asymmetric Epoxidation ◽  
Aqueous Hydrogen Peroxide
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