Asymmetric Oxidation Catalysis by a Chiral Al(salalen) Complex: Highly Enantioselective Oxidation of Sulfides with Aqueous Hydrogen Peroxide

2007 ◽  
Vol 46 (25) ◽  
pp. 4729-4731 ◽  
Author(s):  
Tetsufumi Yamaguchi ◽  
Kazuhiro Matsumoto ◽  
Bunnai Saito ◽  
Tsutomu Katsuki
Keyword(s):  
Hydrogen Peroxide ◽  
Oxidation Catalysis ◽  
Aqueous Hydrogen Peroxide ◽  
Asymmetric Oxidation ◽  
Enantioselective Oxidation ◽  
Oxidation Of Sulfides

scholarly journals Metal-Organic Frameworks in Oxidation Catalysis with Hydrogen Peroxide

Catalysts ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 283
Author(s):  
Oxana Kholdeeva ◽  
Nataliya Maksimchuk
Keyword(s):  
Hydrogen Peroxide ◽  
Liquid Phase ◽  
Selective Oxidation ◽  
Metal Organic Frameworks ◽  
Short Review ◽  
Catalytic Performance ◽  
Oxidation Catalysis ◽  
Catalyst Stability ◽  
Aqueous Hydrogen Peroxide ◽  
Metal Organic

In recent years, metal–organic frameworks (MOFs) have received increasing attention as selective oxidation catalysts and supports for their construction. In this short review paper, we survey recent findings concerning use of MOFs in heterogeneous liquid-phase selective oxidation catalysis with the green oxidant–aqueous hydrogen peroxide. MOFs having outstanding thermal and chemical stability, such as Cr(III)-based MIL-101, Ti(IV)-based MIL-125, Zr(IV)-based UiO-66(67), Zn(II)-based ZIF-8, and some others, will be in the main focus of this work. The effects of the metal nature and MOF structure on catalytic activity and oxidation selectivity are analyzed and the mechanisms of hydrogen peroxide activation are discussed. In some cases, we also make an attempt to analyze relationships between liquid-phase adsorption properties of MOFs and peculiarities of their catalytic performance. Attempts of using MOFs as supports for construction of single-site catalysts through their modification with heterometals will be also addressed in relation to the use of such catalysts for activation of H2O2. Special attention is given to the critical issues of catalyst stability and reusability. The scope and limitations of MOF catalysts in H2O2-based selective oxidation are discussed.

Microencapsulated Chloroperoxidase as a Recyclable Catalyst for the Enantioselective Oxidation of Sulfides with Hydrogen Peroxide

2004 ◽  
Vol 116 (31) ◽  
pp. 4189-4191 ◽  
Author(s):  
Valentina Trevisan ◽  
Michela Signoretto ◽  
Stefano Colonna ◽  
Vincenza Pironti ◽  
Giorgio Strukul
Keyword(s):  
Hydrogen Peroxide ◽  
Recyclable Catalyst ◽  
Enantioselective Oxidation ◽  
Oxidation Of Sulfides

ChemInform Abstract: Highly Enantioselective Catalytic Asymmetric Oxidation of Sulfides Using Hydrogen Peroxide.

ChemInform ◽  
2010 ◽  
Vol 26 (47) ◽  
pp. no-no
Author(s):  
P. C. B. PAGE ◽  
J. P. HEER ◽  
D. BETHELL ◽  
E. W. COLLINGTON ◽  
D. M. ANDREWS
Keyword(s):  
Hydrogen Peroxide ◽  
Asymmetric Oxidation ◽  
Oxidation Of Sulfides ◽  
Catalytic Asymmetric

Copper-Catalyzed Oxidation of Sulfides to Sulfoxides with Aqueous Hydrogen Peroxide.

ChemInform ◽  
2005 ◽  
Vol 36 (37) ◽  
Author(s):  
Subbarayan Velusamy ◽  
Akkilagunta V. Kumar ◽  
Rakesh Saini ◽  
T. Punniyamurthy
Keyword(s):  
Hydrogen Peroxide ◽  
Aqueous Hydrogen Peroxide ◽  
Oxidation Of Sulfides ◽  
Catalyzed Oxidation

Bimetallic titanium complex catalyzed enantioselective oxidation of thioethers using aqueous H2O2 as a terminal oxidant

RSC Advances ◽  
2015 ◽  
Vol 5 (59) ◽  
pp. 47732-47739 ◽  
Author(s):  
Prasanta Kumar Bera ◽  
Naveen Gupta ◽  
Sayed H. R. Abdi ◽  
Noor-ul H. Khan ◽  
Rukhsana I. Kureshy ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Catalytic System ◽  
Sulfide Oxidation ◽  
Environmentally Benign ◽  
Aqueous Hydrogen Peroxide ◽  
Titanium Complex ◽  
Enantioselective Oxidation ◽  
Highly Efficient

This study represents a highly efficient sulfide oxidation catalytic system using a non-toxic Ti-catalyst and environmentally benign aqueous hydrogen peroxide.

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