scholarly journals Highly Stereo- and Regioselective Synthesis of (Z)-Trisubstituted Alkenes via 1-Bromo-1-alkyne Hydroboration−Migratory Insertion−Zn-Promoted Iodinolysis and Pd-Catalyzed Organozinc Cross-Coupling

2007 ◽  
Vol 129 (47) ◽  
pp. 14788-14792 ◽  
Author(s):  
Zhihong Huang ◽  
Ei-ichi Negishi
Keyword(s):  
Cross Coupling ◽  
Regioselective Synthesis ◽  
Migratory Insertion ◽  
Trisubstituted Alkenes

Directed Metalation–Suzuki–Miyaura Cross-Coupling Strategies: Regioselective Synthesis of Hydroxylated 1-Methyl-phenanthrenes

2015 ◽  
Vol 80 (19) ◽  
pp. 9410-9424 ◽  
Author(s):  
Kåre B. Jørgensen ◽  
Toni Rantanen ◽  
Thilo Dörfler ◽  
Victor Snieckus
Keyword(s):  
Cross Coupling ◽  
Regioselective Synthesis ◽  
Coupling Strategies

Palladium-catalyzed regioselective synthesis of B(4,5)- or B(4)-substituted o-carboranes containing α,β-unsaturated carbonyls

2020 ◽  
Vol 18 (25) ◽  
pp. 4723-4727 ◽  
Author(s):  
Chuyi Zhang ◽  
Qian Wang ◽  
Song Tian ◽  
Jianwei Zhang ◽  
Jiaoyi Li ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Regioselective Synthesis ◽  
Cross Coupling Reaction ◽  
Unsaturated Carbonyls ◽  
Palladium Catalyzed

B(4,5)- or B(4)-Substituted o-carboranes containing α,β-unsaturated carbonyls are regioselectively synthesized through a Pd-catalyzed decarboxylation cross coupling reaction.

RhI-Catalyzed Stille-Type Coupling of Diazoesters with Aryl Trimethylstannanes

2015 ◽  
Vol 68 (9) ◽  
pp. 1379 ◽  
Author(s):  
Zhen Liu ◽  
Ying Xia ◽  
Sheng Feng ◽  
Shuai Wang ◽  
Di Qiu ◽  
...  
Keyword(s):  
Diazo Compound ◽  
Cross Coupling ◽  
Mild Conditions ◽  
Alternative Approach ◽  
Migratory Insertion ◽  
Type Coupling ◽  
Insertion Process ◽  
Coupling Partner

A RhI-catalyzed cross-coupling of diazoester with arylstannane was developed. This reaction represents the first Stille-type coupling that uses a diazo compound as the coupling partner. The reaction is operationally simple and can be carried out under mild conditions, thus providing an alternative approach for the synthesis of α-aryl esters. RhI–carbene migratory insertion process is suggested to be involved as the key step in this Stille-type coupling.

Palladium-Catalyzed Oxygenative Cross-Coupling of Ynamides and Benzyl Bromides by Carbene Migratory Insertion

2018 ◽  
Vol 130 (10) ◽  
pp. 2746-2750 ◽  
Author(s):  
Yunpeng Gao ◽  
Guojiao Wu ◽  
Qi Zhou ◽  
Jianbo Wang
Keyword(s):  
Cross Coupling ◽  
Migratory Insertion ◽  
Palladium Catalyzed
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