Directed Metalation–Suzuki–Miyaura Cross-Coupling Strategies: Regioselective Synthesis of Hydroxylated 1-Methyl-phenanthrenes

2015 ◽  
Vol 80 (19) ◽  
pp. 9410-9424 ◽  
Author(s):  
Kåre B. Jørgensen ◽  
Toni Rantanen ◽  
Thilo Dörfler ◽  
Victor Snieckus
Keyword(s):  
Cross Coupling ◽  
Regioselective Synthesis ◽  
Coupling Strategies

ChemInform Abstract: Directed Metalation-Suzuki-Miyaura Cross-Coupling Strategies: Regioselective Synthesis of Hydroxylated 1-Methyl-phenanthrenes.

ChemInform ◽  
2016 ◽  
Vol 47 (9) ◽  
pp. no-no
Author(s):  
Kaare B. Joergensen ◽  
Toni Rantanen ◽  
Thilo Doerfler ◽  
Victor Snieckus
Keyword(s):  
Cross Coupling ◽  
Regioselective Synthesis ◽  
Coupling Strategies

Integrated Pd-catalyzed cross-coupling strategies for furnishing α-carbolines

Tetrahedron ◽  
2017 ◽  
Vol 73 (40) ◽  
pp. 5946-5958 ◽  
Author(s):  
Misayo Sera ◽  
Hideya Mizufune ◽  
Tsuyoshi Ueda ◽  
Masahiro Mineno ◽  
Atsuhiko Zanka
Keyword(s):  
Cross Coupling ◽  
Coupling Strategies

Cross Coupling Strategies towards the Synthesis of the Streptonigrin CD Moiety

Heterocycles ◽  
1999 ◽  
Vol 51 (4) ◽  
pp. 721 ◽  
Author(s):  
Cedric W. Holzapfel ◽  
Renier Crous ◽  
Catherine Dwyer
Keyword(s):  
Cross Coupling ◽  
Coupling Strategies

Recent Developments in C–C Bond Formation Using Catalytic Reductive Coupling Strategies

Synthesis ◽  
2020 ◽  
Vol 52 (18) ◽  
pp. 2623-2638
Author(s):  
Joshua D. Sieber ◽  
Toolika Agrawal
Keyword(s):  
Bond Formation ◽  
Cross Coupling ◽  
Short Review ◽  
Reductive Coupling ◽  
Recent Developments ◽  
Molecular Complexity ◽  
Metal Catalyzed ◽  
Coupling Processes ◽  
Coupling Strategies

Metal-catalyzed reductive coupling processes have emerged as a powerful methodology for the introduction of molecular complexity from simple starting materials. These methods allow for an orthogonal approach to that of redox-neutral strategies for the formation of C–C bonds by enabling cross-coupling of starting materials not applicable to redox-neutral chemistry. This short review summarizes the most recent developments in the area of metal-catalyzed reductive coupling utilizing catalyst turnover by a stoichiometric reductant that becomes incorporated in the final product.1 Introduction2 Ni Catalysis3 Cu Catalysis4 Ru, Rh, and Ir Catalysis4.1 Alkenes4.2 1,3-Dienes4.3 Allenes4.4 Alkynes4.5 Enynes5 Fe, Co, and Mn Catalysis6 Conclusion and Outlook

Azaheterocyclic Derivatives of ortho-Carborane: Synthetic Strategies and Application Opportunities

Synthesis ◽  
2019 ◽  
Vol 52 (03) ◽  
pp. 337-352 ◽  
Author(s):  
Lidiia A. Smyshliaeva ◽  
Mikhail V. Varaksin ◽  
Valery N. Charushin ◽  
Oleg N. Chupakhin
Keyword(s):  
Materials Science ◽  
Cross Coupling ◽  
General Character ◽  
Advanced Technologies ◽  
Substituted Acetylenes ◽  
Synthetic Approaches ◽  
Derivatives Of ◽  
Coupling Strategies

Azaheterocyclic derivatives of 1,2-dicarba-closo-dodeca­borane (ortho-carborane) are known to be of particular interest due to numerous plausible applications, particularly, in medicine, materials science, and advanced technologies. Three principal synthetic strategies resulting in azaheterocyclic carboranes, in which boron-enriched and azaheterocyclic fragments are linked to each other, either directly by means of the C–C bonds or through a short spacer (CH2, CH2S, CH2O, etc.), have been outlined. These synthetic approaches are of general character and can be used both individually and in combination to afford promising organoboron clusters of diverse architectures.1 Introduction2 C–C Cross-Coupling Strategies in the Synthesis of Azahetero­cyclic Carboranes3 Carboryne-Based Transformation Strategies4 Condensation Strategies: Reactions of Decaborane B10H14 with Substituted Acetylenes5 Conclusion and Outlook

Palladium-catalyzed regioselective synthesis of B(4,5)- or B(4)-substituted o-carboranes containing α,β-unsaturated carbonyls

2020 ◽  
Vol 18 (25) ◽  
pp. 4723-4727 ◽  
Author(s):  
Chuyi Zhang ◽  
Qian Wang ◽  
Song Tian ◽  
Jianwei Zhang ◽  
Jiaoyi Li ◽  
...  
Keyword(s):  
Coupling Reaction ◽  
Cross Coupling ◽  
Regioselective Synthesis ◽  
Cross Coupling Reaction ◽  
Unsaturated Carbonyls ◽  
Palladium Catalyzed

B(4,5)- or B(4)-Substituted o-carboranes containing α,β-unsaturated carbonyls are regioselectively synthesized through a Pd-catalyzed decarboxylation cross coupling reaction.

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