Mechanistic Study of Hydrogen Transfer to Imines from a Hydroxycyclopentadienyl Ruthenium Hydride. Experimental Support for a Mechanism Involving Coordination of Imine to Ruthenium Prior to Hydrogen Transfer

Joseph S. M. Samec; Alida H. Éll; Jenny B. Åberg; Timofei Privalov; Lars Eriksson; Jan-E. Bäckvall

doi:10.1021/ja061494o

Mechanistic Study of Hydrogen Transfer to Imines from a Hydroxycyclopentadienyl Ruthenium Hydride. Experimental Support for a Mechanism Involving Coordination of Imine to Ruthenium Prior to Hydrogen Transfer

Journal of the American Chemical Society ◽

10.1021/ja061494o ◽

2006 ◽

Vol 128 (44) ◽

pp. 14293-14305 ◽

Cited By ~ 101

Author(s):

Joseph S. M. Samec ◽

Alida H. Éll ◽

Jenny B. Åberg ◽

Timofei Privalov ◽

Lars Eriksson ◽

...

Keyword(s):

Hydrogen Transfer ◽

Mechanistic Study ◽

Ruthenium Hydride ◽

Experimental Support ◽

Hydroxycyclopentadienyl Ruthenium Hydride

Download Full-text

Mechanism of hydrogen transfer to imines from a hydroxycyclopentadienyl ruthenium hydride. Support for a stepwise mechanism

Chemical Communications ◽

10.1039/b410698a ◽

2004 ◽

pp. 2748-2749 ◽

Cited By ~ 44

Author(s):

Joseph S. M. Samec ◽

Alida H. Éll ◽

Jan-E. Bäckvall

Keyword(s):

Hydrogen Transfer ◽

Stepwise Mechanism ◽

Ruthenium Hydride ◽

Hydroxycyclopentadienyl Ruthenium Hydride

Download Full-text

Hydrogen Transfer to Carbonyls and Imines from a Hydroxycyclopentadienyl Ruthenium Hydride: Evidence for Concerted Hydride and Proton Transfer

Journal of the American Chemical Society ◽

10.1021/ja002177z ◽

2001 ◽

Vol 123 (6) ◽

pp. 1090-1100 ◽

Cited By ~ 252

Author(s):

Charles P. Casey ◽

Steven W. Singer ◽

Douglas R. Powell ◽

Randy K. Hayashi ◽

Michael Kavana

Keyword(s):

Proton Transfer ◽

Hydrogen Transfer ◽

Ruthenium Hydride ◽

Hydroxycyclopentadienyl Ruthenium Hydride

Download Full-text

DFT Study of an Inner-Sphere Mechanism in the Hydrogen Transfer from a Hydroxycyclopentadienyl Ruthenium Hydride to Imines

Organometallics ◽

10.1021/om070169m ◽

2007 ◽

Vol 26 (11) ◽

pp. 2840-2848 ◽

Cited By ~ 42

Author(s):

Timofei Privalov ◽

Joseph S. M. Samec ◽

Jan-E. Bäckvall

Keyword(s):

Hydrogen Transfer ◽

Dft Study ◽

Ruthenium Hydride ◽

Inner Sphere ◽

Hydroxycyclopentadienyl Ruthenium Hydride ◽

Sphere Mechanism

Download Full-text

Reduction of Imines by Hydroxycyclopentadienyl Ruthenium Hydride: Intramolecular Trapping Evidence for Hydride and Proton Transfer Outside the Coordination Sphere of the Metal

Journal of the American Chemical Society ◽

10.1021/ja053956o ◽

2005 ◽

Vol 127 (40) ◽

pp. 14062-14071 ◽

Cited By ~ 91

Author(s):

Charles P. Casey ◽

Galina A. Bikzhanova ◽

Qiang Cui ◽

Ilia A. Guzei

Keyword(s):

Proton Transfer ◽

Coordination Sphere ◽

Ruthenium Hydride ◽

Hydroxycyclopentadienyl Ruthenium Hydride

Download Full-text

ChemInform Abstract: A Kinetic and Mechanistic Study of Cyclohexene Disproportionation: An Example of Irreversible Hydrogen Transfer.

ChemInform ◽

10.1002/chin.198838085 ◽

1988 ◽

Vol 19 (38) ◽

Author(s):

D. M. REBHAN ◽

V. HAENSEL

Keyword(s):

Hydrogen Transfer ◽

Mechanistic Study

Download Full-text

Computational Mechanistic Study on Cp*Ir Complex-Mediated Acceptorless Alcohol Dehydrogenation: Bifunctional Hydrogen Transfer vs β-H Elimination

Organometallics ◽

10.1021/om200089m ◽

2011 ◽

Vol 30 (8) ◽

pp. 2349-2363 ◽

Cited By ~ 59

Author(s):

Haixia Li ◽

Gang Lu ◽

Jinliang Jiang ◽

Fang Huang ◽

Zhi-Xiang Wang

Keyword(s):

Hydrogen Transfer ◽

Mechanistic Study ◽

Alcohol Dehydrogenation ◽

Acceptorless Alcohol Dehydrogenation

Download Full-text

Intramolecular Trapping of an Intermediate in the Reduction of Imines by a Hydroxycyclopentadienyl Ruthenium Hydride: Support for a Concerted Outer Sphere Mechanism

Journal of the American Chemical Society ◽

10.1021/ja073370x ◽

2007 ◽

Vol 129 (38) ◽

pp. 11821-11827 ◽

Cited By ~ 76

Author(s):

Charles P. Casey ◽

Timothy B. Clark ◽

Ilia A. Guzei

Keyword(s):

Outer Sphere ◽

Ruthenium Hydride ◽

Hydroxycyclopentadienyl Ruthenium Hydride ◽

Sphere Mechanism

Download Full-text

Hydrogen Transfer to Ketones Catalyzed by Shvo's Ruthenium Hydride Complex: A Mechanistic Insight

Organometallics ◽

10.1021/om7004832 ◽

2007 ◽

Vol 26 (17) ◽

pp. 4135-4144 ◽

Cited By ~ 104

Author(s):

Aleix Comas-Vives ◽

Gregori Ujaque ◽

Agustí Lledós

Keyword(s):

Hydrogen Transfer ◽

Ruthenium Hydride ◽

Hydride Complex ◽

Mechanistic Insight

Download Full-text

A kinetic and mechanistic study of cyclohexene disproportionation: An example of irreversible hydrogen transfer

Journal of Catalysis ◽

10.1016/0021-9517(88)90098-x ◽

1988 ◽

Vol 111 (2) ◽

pp. 397-408 ◽

Cited By ~ 19

Author(s):

D REBHAN

Keyword(s):

Hydrogen Transfer ◽

Mechanistic Study

Download Full-text

Investigation of a Possible Solvent Cage Effect in the Reduction of 4-Aminocyclohexanone by a Hydroxycyclopentadienyl Ruthenium Hydride

Chemistry - A European Journal ◽

10.1002/chem.200801195 ◽

2008 ◽

Vol 14 (30) ◽

pp. 9169-9174 ◽

Cited By ~ 9

Author(s):

Jenny B. Åberg ◽

Jan-E. Bäckvall

Keyword(s):

Cage Effect ◽

Ruthenium Hydride ◽

Solvent Cage ◽

Hydroxycyclopentadienyl Ruthenium Hydride

Download Full-text