Reduction of Imines by Hydroxycyclopentadienyl Ruthenium Hydride:  Intramolecular Trapping Evidence for Hydride and Proton Transfer Outside the Coordination Sphere of the Metal

2005 ◽  
Vol 127 (40) ◽  
pp. 14062-14071 ◽  
Author(s):  
Charles P. Casey ◽  
Galina A. Bikzhanova ◽  
Qiang Cui ◽  
Ilia A. Guzei
Keyword(s):  
Proton Transfer ◽  
Coordination Sphere ◽  
Ruthenium Hydride ◽  
Hydroxycyclopentadienyl Ruthenium Hydride

Hydrogen Bonding and Proton Transfer to Ruthenium Hydride Complex CpRuH(dppe): Metal and Hydride Dichotomy

2013 ◽  
Vol 52 (4) ◽  
pp. 1787-1797 ◽  
Author(s):  
Gleb A. Silantyev ◽  
Oleg A. Filippov ◽  
Peter M. Tolstoy ◽  
Natalia V. Belkova ◽  
Lina M. Epstein ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Proton Transfer ◽  
Ruthenium Hydride ◽  
Hydride Complex

Influence of a Pendant Amine in the Second Coordination Sphere on Proton Transfer at a Dissymmetrically Disubstituted Diiron System Related to the [2Fe]HSubsite of [FeFe]H2ase

2009 ◽  
Vol 48 (1) ◽  
pp. 2-4 ◽  
Author(s):  
Salah Ezzaher ◽  
Jean-François Capon ◽  
Frédéric Gloaguen ◽  
François Y. Pétillon ◽  
Philippe Schollhammer ◽  
...  
Keyword(s):  
Proton Transfer ◽  
Coordination Sphere ◽  
Second Coordination Sphere

Mechanism of C–P bond formation via Pd-catalyzed decarbonylative phosphorylation of amides: insight into the chemistry of the second coordination sphere

2020 ◽  
Vol 56 (1) ◽  
pp. 113-116
Author(s):  
Wen-Yan Tong ◽  
Thu D. Ly ◽  
Tao-Tao Zhao ◽  
Yan-Bo Wu ◽  
Xiaotai Wang
Keyword(s):  
Reaction Mechanism ◽  
Proton Transfer ◽  
Coordination Sphere ◽  
Bond Formation ◽  
Dft Computations ◽  
Detailed Reaction Mechanism ◽  
Non Covalent Interactions ◽  
Second Coordination Sphere ◽  
Covalent Interactions ◽  
Insight Into

DFT computations establish a detailed reaction mechanism for the first Pd-catalyzed decarbonylative phosphorylation of amides forming C–P bonds, which includes non-covalent interactions as well as proton transfer in the second coordination sphere.

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