Identification and Characterization of Monoanionic Tripodal Tetradentate Ligand Complexes of Copper(I) and Copper(II) Involved in Halogen Atom Transfer Reactions

2004 ◽  
Vol 126 (44) ◽  
pp. 14352-14353 ◽  
Author(s):  
Jocelyn M. Goodwin ◽  
Marilyn M. Olmstead ◽  
Timothy E. Patten
Keyword(s):  
Halogen Atom ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Tetradentate Ligand ◽  
Atom Transfer Reactions ◽  
Identification And Characterization

Characterization of Cu(II) Bipyridine Complexes in Halogen Atom Transfer Reactions by Electron Spin Resonance

2003 ◽  
Vol 36 (22) ◽  
pp. 8291-8296 ◽  
Author(s):  
Bernhard Knuehl ◽  
Tomislav Pintauer ◽  
Atsushi Kajiwara ◽  
Hanns Fischer ◽  
Krzysztof Matyjaszewski
Keyword(s):  
Electron Spin Resonance ◽  
Electron Spin ◽  
Halogen Atom ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Spin Resonance ◽  
Atom Transfer Reactions

scholarly journals Formation and characterization of a reactive chromium(v)–oxo complex: mechanistic insight into hydrogen-atom transfer reactions

2015 ◽  
Vol 6 (2) ◽  
pp. 945-955 ◽  
Author(s):  
Hiroaki Kotani ◽  
Suzue Kaida ◽  
Tomoya Ishizuka ◽  
Miyuki Sakaguchi ◽  
Takashi Ogura ◽  
...  
Keyword(s):  
Hydrogen Atom ◽  
Reaction Mechanisms ◽  
Hydrogen Atom Transfer ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxidation Potentials ◽  
Mechanistic Insight ◽  
Atom Transfer Reactions ◽  
Insight Into

Mechanistic insights were gained into hydrogen-atom transfer reactions from benzyl alcohol derivatives with different oxidation potentials to a highly reactive Cr(v)–oxo complex to reveal switching of reaction mechanisms.

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