Gas-Phase Kinetics and Mechanism of the Reactions of Protonated Hydrazine with Carbonyl Compounds. Gas-Phase Hydrazone Formation:  Kinetics and Mechanism

2004 ◽  
Vol 126 (9) ◽  
pp. 2744-2754 ◽  
Author(s):  
Thomas G. Custer ◽  
Shuji Kato ◽  
Veronica M. Bierbaum ◽  
Carleton J. Howard ◽  
Glenn C. Morrison
Keyword(s):  
Gas Phase ◽  
Carbonyl Compounds ◽  
Kinetics And Mechanism ◽  
Gas Phase Kinetics ◽  
Formation Kinetics

Photo-oxidation of Dimethyl Malonate Initiated by Chlorine Atoms in Gas Phase: Kinetics and Mechanism

2017 ◽  
Vol 121 (45) ◽  
pp. 8577-8582 ◽  
Author(s):  
Guido N. Rimondino ◽  
Diana P. Henao ◽  
Walter J. Peláez ◽  
Gustavo A. Argüello ◽  
Fabio E. Malanca
Keyword(s):  
Gas Phase ◽  
Kinetics And Mechanism ◽  
Dimethyl Malonate ◽  
Chlorine Atoms ◽  
Photo Oxidation ◽  
Gas Phase Kinetics

scholarly journals Theoretical studies on gas-phase kinetics and mechanism of H-abstraction reaction from methanol by ClO and BrO radicals

RSC Advances ◽  
2015 ◽  
Vol 5 (49) ◽  
pp. 39110-39121 ◽  
Author(s):  
Samiyara Begum ◽  
Ranga Subramanian
Keyword(s):  
Gas Phase ◽  
Theoretical Approach ◽  
Kinetics And Mechanism ◽  
Theoretical Studies ◽  
Gas Phase Kinetics ◽  
Abstraction Reaction

The gas-phase kinetics and mechanism of two channel hydrogen (H) abstraction reaction either hydroxyl H-atom or methyl H-atom from methanol (CH3OH) by halogen monoxide (XO, X = Cl, Br) radical have been investigated using theoretical approach.

Kinetic Analysis of C4 Alkane and Alkene Pyrolysis: Implications for SOFC Operation

2010 ◽  
Vol 7 (4) ◽  
Author(s):  
Ahmed Al Shoaibi ◽  
Anthony M. Dean
Keyword(s):  
Gas Phase ◽  
Solid Oxide ◽  
Oxide Fuel ◽  
Pyrolysis Kinetics ◽  
Fuel Conversion ◽  
Substantial Impact ◽  
Gas Phase Chemistry ◽  
Gas Phase Kinetics ◽  
Hydrocarbon Gas ◽  
Phase Chemistry

Pyrolysis experiments of isobutane, isobutylene, and 1-butene were performed over a temperature range of 550–750°C and a pressure of ∼0.8 atm. The residence time was ∼5 s. The fuel conversion and product selectivity were analyzed at these temperatures. The pyrolysis experiments were performed to simulate the gas-phase chemistry that occurs in the anode channel of a solid-oxide fuel cell (SOFC). The experimental results confirm that molecular structure has a substantial impact on pyrolysis kinetics. The experimental data show considerable amounts of C5 and higher species (∼2.8 mole % with isobutane at 750°C, ∼7.5 mole % with isobutylene at 737.5°C, and ∼7.4 mole % with 1-butene at 700°C). The C5+ species are likely deposit precursors. The results confirm that hydrocarbon gas-phase kinetics have substantial impact on a SOFC operation.

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