Calorimetry of Polymer Metallization:  Copper, Calcium, and Chromium on PMDA-ODA Polyimide

2003 ◽  
Vol 125 (13) ◽  
pp. 3995-3998 ◽  
Author(s):  
Richard Murdey ◽  
J. Todd Stuckless
Author(s):  
Dmitry Filonov ◽  
Sergey Kolen ◽  
Andrey Shmidt ◽  
Yosi Shacham‐Diamand ◽  
Amir Boag ◽  
...  

2002 ◽  
pp. 73-96 ◽  
Author(s):  
F. Faupel ◽  
V. Zaporojtchenko ◽  
T. Strunskus ◽  
J. Erichsen ◽  
K. Dolgner ◽  
...  

1998 ◽  
Vol 511 ◽  
Author(s):  
F. Faupel ◽  
T. Strunskus ◽  
M. Kiene ◽  
A. Thran ◽  
C. V. Bechtolsheim ◽  
...  

ABSTRACTValuable information on the structure and formation of metal-polymer interfaces originates from radiotracer measurements of metal diffusion at the interface, structural investigations by means of transmission electron microscopy, and computer simulations on the interplay of atomic metal diffusion and aggregation. Moreover, X-ray photoemission spectroscopy has largely contributed to our present understanding of the interfacial chemistry and the early stages of interface formation. While reactive metals always form relatively sharp interfaces with polymers, metals of lower reactivity diffuse into polymers at elevated temperatures and have a very strong tendency to agglomerate. The extent of diffusion appears to be determined by the initial stage of the deposition process. Here sticking coefficients recently measured for metals on virgin polymer surfaces deviate markedly from unity. Diffusion into the polymer increases strongly at low deposition rates. No significant diffusion is expected from a continuous metal film unless metal ions are formed at the interface. Metal ions are highly mobile and do not aggregate due to electrostatic repulsion. The model emerging from these observations allows us to predict the salient features of interface formation between metals and polymers in general and particularly with respect to the new low-k polymers.


2013 ◽  
Vol 160 (9) ◽  
pp. D417-D421 ◽  
Author(s):  
Atsushi Kitada ◽  
Kozo Yanase ◽  
Takashi Ichii ◽  
Hiroyuki Sugimura ◽  
Kuniaki Murase

2015 ◽  
Vol 760 ◽  
pp. 263-268 ◽  
Author(s):  
Gheorghe Amza ◽  
Dan Nitoi ◽  
Cătălin Amza ◽  
Zoia Apostolescu ◽  
Constantin Gheorghe Opran

Paper presents ultrasonic system design and calculation for metallization process of the polymer pieces. Because of some bad properties like: very low hardness, very low wear resistance, no electrical conductivity and no open fire resistance, polymer parts has to be reinforced with different materials. A new method is represented by ultrasonic field metallization process which has certain advantages. The work presents the analytic calculation for the ultrasonic field and vibration modes of the ultrasonic system used for a polymer base material ultrasonic activation.


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