Carbon−Hydrogen Bond Activation by Titanium Imido Complexes. Computational Evidence for the Role of Alkane Adducts in Selective C−H Activation

Thomas R. Cundari; Thomas R. Klinckman; Peter T. Wolczanski

doi:10.1021/ja016248l

Carbon−Hydrogen Bond Activation by Titanium Imido Complexes. Computational Evidence for the Role of Alkane Adducts in Selective C−H Activation

Journal of the American Chemical Society ◽

10.1021/ja016248l ◽

2002 ◽

Vol 124 (7) ◽

pp. 1481-1487 ◽

Cited By ~ 75

Author(s):

Thomas R. Cundari ◽

Thomas R. Klinckman ◽

Peter T. Wolczanski

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Imido Complexes ◽

Carbon Hydrogen Bond Activation

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Role of oxide surface radicals for methane carbon-hydrogen bond activation and subsequent reactions on molybdena: molecular orbital theory

The Journal of Physical Chemistry ◽

10.1021/j100295a056 ◽

1987 ◽

Vol 91 (11) ◽

pp. 2930-2934 ◽

Cited By ~ 34

Author(s):

S. P. Mehandru ◽

Alfred B. Anderson ◽

James F. Brazdil ◽

Robert K. Grasselli

Keyword(s):

Hydrogen Bond ◽

Molecular Orbital ◽

Bond Activation ◽

Oxide Surface ◽

Molecular Orbital Theory ◽

Orbital Theory ◽

Carbon Hydrogen Bond Activation ◽

Methane Carbon

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Control of .eta.2-coordination vs. carbon-hydrogen bond activation by rhodium: the role of aromatic resonance energies

Journal of the American Chemical Society ◽

10.1021/ja00070a012 ◽

1993 ◽

Vol 115 (17) ◽

pp. 7685-7695 ◽

Cited By ~ 43

Author(s):

R. Martin Chin ◽

Lingzhen Dong ◽

Simon B. Duckett ◽

Martin G. Partridge ◽

William D. Jones ◽

...

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Resonance Energies ◽

Carbon Hydrogen Bond Activation

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Carbon-hydrogen bond activation as the initial step in the Co+-mediated demethanation of propane: the critical role of angular momentum at the rate-limiting transition state

Journal of the American Chemical Society ◽

10.1021/ja00170a054 ◽

1990 ◽

Vol 112 (14) ◽

pp. 5663-5665 ◽

Cited By ~ 37

Author(s):

Petra A. M. Van Koppen ◽

J. Brodbelt-Lustig ◽

Michael T. Bowers ◽

David V. Dearden ◽

J. L. Beauchamp ◽

...

Keyword(s):

Hydrogen Bond ◽

Angular Momentum ◽

Transition State ◽

Bond Activation ◽

Critical Role ◽

Initial Step ◽

Carbon Hydrogen Bond Activation ◽

Rate Limiting

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Pd‐Au Supported Reduced Graphene Oxide Catalyst for Carbon‐ Hydrogen Bond Activation in Benzene

ChemistrySelect ◽

10.1002/slct.202101988 ◽

2021 ◽

Vol 6 (28) ◽

pp. 7111-7117

Author(s):

Deepika Sharma ◽

Kamal Kishor Thakur ◽

Neeraj Gupta

Keyword(s):

Hydrogen Bond ◽

Graphene Oxide ◽

Reduced Graphene Oxide ◽

Oxide Catalyst ◽

Bond Activation ◽

Reduced Graphene ◽

Carbon Hydrogen Bond Activation

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Modeling the Proposed Intermediate in Alkane Carbon−Hydrogen Bond Activation by Cp*(PMe3)Ir(Me)OTf: Synthesis and Stability of Novel Organometallic Iridium(V) Complexes

Organometallics ◽

10.1021/om990255p ◽

1999 ◽

Vol 18 (14) ◽

pp. 2707-2717 ◽

Cited By ~ 39

Author(s):

Peter J. Alaimo ◽

Robert G. Bergman

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Carbon Hydrogen Bond Activation

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Photochemical generation of reactive transition-metal intermediates from air-stable precursors. Carbon-hydrogen bond activation via near-ultraviolet photolysis of CpIr(L)(oxalate) and CpIr(L)(N3)2 complexes

Inorganic Chemistry ◽

10.1021/ic00004a043 ◽

1991 ◽

Vol 30 (4) ◽

pp. 836-840 ◽

Cited By ~ 16

Author(s):

Daniel A. Freedman ◽

Kent R. Mann

Keyword(s):

Hydrogen Bond ◽

Transition Metal ◽

Bond Activation ◽

Photochemical Generation ◽

Near Ultraviolet ◽

Carbon Hydrogen Bond Activation ◽

Ultraviolet Photolysis

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Carbon-hydrogen bond activation using a bis(phosphine)iridium carbonyl hydride and the carbonylation of benzene

Organometallics ◽

10.1021/om00078a013 ◽

1983 ◽

Vol 2 (6) ◽

pp. 764-767 ◽

Cited By ~ 42

Author(s):

Barbara J. Fisher ◽

Richard Eisenberg

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Carbon Hydrogen Bond Activation

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Aromatic and aldehyde carbon–hydrogen bond activation at cationic Rh(III) centers. Evaluation of electronic substituent effects on aldehyde binding and C–H oxidative addition

Polyhedron ◽

10.1016/j.poly.2004.09.005 ◽

2004 ◽

Vol 23 (17) ◽

pp. 2943-2954 ◽

Cited By ~ 23

Author(s):

Britton K. Corkey ◽

Felicia L. Taw ◽

Robert G. Bergman ◽

Maurice Brookhart

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Oxidative Addition ◽

Substituent Effects ◽

Carbon Hydrogen Bond Activation

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Cationic η2-arene complexes of rhenium in carbon-hydrogen bond activation

Journal of the American Chemical Society ◽

10.1021/ja00340a033 ◽

1983 ◽

Vol 105 (2) ◽

pp. 305-306 ◽

Cited By ~ 30

Author(s):

James R. Sweet ◽

William A. G. Graham

Keyword(s):

Hydrogen Bond ◽

Bond Activation ◽

Arene Complexes ◽

Carbon Hydrogen Bond Activation

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Orthometallation in iridium N-heterocycle stabilized carbene complexes via carbon halogen and carbon hydrogen bond activation induced by silver nanoparticles

Inorganica Chimica Acta ◽

10.1016/j.ica.2018.10.016 ◽

2019 ◽

Vol 486 ◽

pp. 1-7 ◽

Cited By ~ 2

Author(s):

Andrew C. Marr ◽

Graham C. Saunders ◽

Hayden P. Thomas ◽

Yue-Ming Wang

Keyword(s):

Hydrogen Bond ◽

Silver Nanoparticles ◽

Bond Activation ◽

Carbene Complexes ◽

Carbon Hydrogen Bond Activation

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Carbon−Hydrogen Bond Activation by Titanium Imido Complexes. Computational Evidence for the Role of Alkane Adducts in Selective C−H Activation

Role of oxide surface radicals for methane carbon-hydrogen bond activation and subsequent reactions on molybdena: molecular orbital theory

Control of .eta.2-coordination vs. carbon-hydrogen bond activation by rhodium: the role of aromatic resonance energies

Carbon-hydrogen bond activation as the initial step in the Co+-mediated demethanation of propane: the critical role of angular momentum at the rate-limiting transition state

Pd‐Au Supported Reduced Graphene Oxide Catalyst for Carbon‐ Hydrogen Bond Activation in Benzene

Modeling the Proposed Intermediate in Alkane Carbon−Hydrogen Bond Activation by Cp*(PMe3)Ir(Me)OTf: Synthesis and Stability of Novel Organometallic Iridium(V) Complexes

Photochemical generation of reactive transition-metal intermediates from air-stable precursors. Carbon-hydrogen bond activation via near-ultraviolet photolysis of Cp*Ir(L)(oxalate) and Cp*Ir(L)(N3)2 complexes

Carbon-hydrogen bond activation using a bis(phosphine)iridium carbonyl hydride and the carbonylation of benzene

Aromatic and aldehyde carbon–hydrogen bond activation at cationic Rh(III) centers. Evaluation of electronic substituent effects on aldehyde binding and C–H oxidative addition

Cationic η2-arene complexes of rhenium in carbon-hydrogen bond activation

Orthometallation in iridium N-heterocycle stabilized carbene complexes via carbon halogen and carbon hydrogen bond activation induced by silver nanoparticles

Photochemical generation of reactive transition-metal intermediates from air-stable precursors. Carbon-hydrogen bond activation via near-ultraviolet photolysis of CpIr(L)(oxalate) and CpIr(L)(N3)2 complexes