Carbon-hydrogen bond activation as the initial step in the Co+-mediated demethanation of propane: the critical role of angular momentum at the rate-limiting transition state

1990 ◽  
Vol 112 (14) ◽  
pp. 5663-5665 ◽  
Author(s):  
Petra A. M. Van Koppen ◽  
J. Brodbelt-Lustig ◽  
Michael T. Bowers ◽  
David V. Dearden ◽  
J. L. Beauchamp ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Angular Momentum ◽  
Transition State ◽  
Bond Activation ◽  
Critical Role ◽  
Initial Step ◽  
Carbon Hydrogen Bond Activation ◽  
Rate Limiting

ChemInform Abstract: C-H Bond Activation as the Initial Step in the Co+-Mediated Demethanation of Propane: The Critical Role of Angular Momentum at the Rate-Limiting Transition State.

ChemInform ◽  
1990 ◽  
Vol 21 (42) ◽  
Author(s):  
P. A. M. VAN KOPPEN ◽  
J. BRODBELT-LUSTIG ◽  
M. T. BOWERS ◽  
D. V. DEARDEN ◽  
J. L. BEAUCHAMP ◽  
...  
Keyword(s):  
Angular Momentum ◽  
Transition State ◽  
Bond Activation ◽  
Critical Role ◽  
Initial Step ◽  
Rate Limiting

Control of .eta.2-coordination vs. carbon-hydrogen bond activation by rhodium: the role of aromatic resonance energies

1993 ◽  
Vol 115 (17) ◽  
pp. 7685-7695 ◽  
Author(s):  
R. Martin Chin ◽  
Lingzhen Dong ◽  
Simon B. Duckett ◽  
Martin G. Partridge ◽  
William D. Jones ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Bond Activation ◽  
Resonance Energies ◽  
Carbon Hydrogen Bond Activation

Transition-State Charge Transfer Reveals Electrophilic, Ambiphilic, and Nucleophilic Carbon−Hydrogen Bond Activation

2009 ◽  
Vol 131 (33) ◽  
pp. 11686-11688 ◽  
Author(s):  
Daniel H. Ess ◽  
Robert J. Nielsen ◽  
William A. Goddard III ◽  
Roy A. Periana
Keyword(s):  
Hydrogen Bond ◽  
Charge Transfer ◽  
Transition State ◽  
Bond Activation ◽  
Carbon Hydrogen Bond Activation ◽  
State Charge
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