Steric Effects in Displacement Reactions. II. The Rates of Reaction of Alkyl Iodide s with the Monoalkylpyridines. Steric Strain in the Activated Complex

Herbert C. Brown; Arno Cahn

doi:10.1021/ja01612a001

Steric Effects in Displacement Reactions. II. The Rates of Reaction of Alkyl Iodide s with the Monoalkylpyridines. Steric Strain in the Activated Complex

Journal of the American Chemical Society ◽

10.1021/ja01612a001 ◽

1955 ◽

Vol 77 (7) ◽

pp. 1715-1723 ◽

Cited By ~ 54

Author(s):

Herbert C. Brown ◽

Arno Cahn

Keyword(s):

Steric Effects ◽

Alkyl Iodide ◽

Steric Strain ◽

Displacement Reactions ◽

Activated Complex

Download Full-text

Steric Effects in Displacement Reactions. IV. Heats of Reaction of Methanesulfonic Acid with the Monoalkylpyridines

Journal of the American Chemical Society ◽

10.1021/ja01612a003 ◽

1955 ◽

Vol 77 (7) ◽

pp. 1727-1730 ◽

Cited By ~ 10

Author(s):

Herbert C. Brown ◽

Robert R. Holmes

Keyword(s):

Methanesulfonic Acid ◽

Steric Effects ◽

Heats Of Reaction ◽

Displacement Reactions

Download Full-text

Steric Effects in Displacement Reactions. III. The Base Strengths of Pyridine, 2,6-Lutidine and the Monoalkylpyridines

Journal of the American Chemical Society ◽

10.1021/ja01612a002 ◽

1955 ◽

Vol 77 (7) ◽

pp. 1723-1726 ◽

Cited By ~ 111

Author(s):

Herbert C. Brown ◽

Xavier R. Mihm

Keyword(s):

Steric Effects ◽

Displacement Reactions

Download Full-text

Steric Effects in Displacement Reactions. VI. The Heats of Formation of the Addition Compounds of Boron Trifluoride with the Monoalkylpyridines. A Linear Relationship Involving Sterically Hindered Reactants1

Journal of the American Chemical Society ◽

10.1021/ja01612a005 ◽

1955 ◽

Vol 77 (7) ◽

pp. 1733-1737 ◽

Cited By ~ 16

Author(s):

Herbert C. Brown ◽

Raymond H. Horowitz

Keyword(s):

Linear Relationship ◽

Boron Trifluoride ◽

Heats Of Formation ◽

Steric Effects ◽

Displacement Reactions ◽

Sterically Hindered

Download Full-text

Steric Effects in Displacement Reactions. IX. Steric Strains in the Reactions of 2,6-Lutidine and 2,4,6-Collidine with Methyl Iodide and with Boron Trifluoride1

Journal of the American Chemical Society ◽

10.1021/ja01601a058 ◽

1956 ◽

Vol 78 (20) ◽

pp. 5375-5377 ◽

Cited By ~ 10

Author(s):

Herbert C. Brown ◽

Daniel Gintis ◽

Harold Podall

Keyword(s):

Methyl Iodide ◽

Steric Effects ◽

Displacement Reactions

Download Full-text

Steric Effects in Elimination Reactions. X. Steric Strains as a Factor in Controlling the Direction of Bimolecular Eliminations. The Hofmann Rule as a Manifestation of Steric Strain

Journal of the American Chemical Society ◽

10.1021/ja01591a050 ◽

1956 ◽

Vol 78 (10) ◽

pp. 2203-2210 ◽

Cited By ~ 27

Author(s):

Herbert C. Brown ◽

I. Moritani

Keyword(s):

Steric Effects ◽

Steric Strain ◽

Elimination Reactions

Download Full-text

Steric Effects in Displacement Reactions. XII. Linear Strain Energy Relationships Involving Reactants of Large Steric Requirements. Steric Strains in the Transition State1

Journal of the American Chemical Society ◽

10.1021/ja01601a061 ◽

1956 ◽

Vol 78 (20) ◽

pp. 5387-5394 ◽

Cited By ~ 36

Author(s):

Herbert C. Brown ◽

Daniel Gintis ◽

Lionel Domash

Keyword(s):

Strain Energy ◽

Steric Effects ◽

Linear Strain ◽

Displacement Reactions ◽

Energy Relationships

Download Full-text

Steric Effects in Displacement Reactions. XI. The Heats of Reaction of Diborane with Pyridine Bases. Steric Strains in Homomorphs of o-t-Butyltoluene and Hemimellitene1

Journal of the American Chemical Society ◽

10.1021/ja01601a060 ◽

1956 ◽

Vol 78 (20) ◽

pp. 5384-5386 ◽

Cited By ~ 34

Author(s):

Herbert C. Brown ◽

Lionel Domash

Keyword(s):

Steric Effects ◽

Pyridine Bases ◽

Heats Of Reaction ◽

Displacement Reactions

Download Full-text

Steric Effects in Displacement Reactions. V. The Heat of Reaction of Pyridine with Boron Trifluoride. A Convenient Calorimeter for Measuring the Heat of Formation of Molecular Addition Compounds

Journal of the American Chemical Society ◽

10.1021/ja01612a004 ◽

1955 ◽

Vol 77 (7) ◽

pp. 1730-1733 ◽

Cited By ~ 9

Author(s):

Herbert C. Brown ◽

Raymond H. Horowitz

Keyword(s):

Boron Trifluoride ◽

Heat Of Formation ◽

Steric Effects ◽

Heat Of Reaction ◽

Displacement Reactions

Download Full-text

Steric Effects in Displacement Reactions. X. A Convenient Calorimeter for Gas-Liquid Reactions. The Heats of Reaction of Trimethylboron with Pyridine and the Monoalkylpyridines1

Journal of the American Chemical Society ◽

10.1021/ja01601a059 ◽

1956 ◽

Vol 78 (20) ◽

pp. 5378-5383 ◽

Cited By ~ 12

Author(s):

Herbert C. Brown ◽

Daniel Gintis

Keyword(s):

Steric Effects ◽

Heats Of Reaction ◽

Displacement Reactions

Download Full-text

Studies in Stereochemistry. XIV. Reaction of Triethylamine and Quinuclidine with Alkyl Halides; Steric Effects in Displacement Reactions

Journal of the American Chemical Society ◽

10.1021/ja01170a020 ◽

1949 ◽

Vol 71 (2) ◽

pp. 445-450 ◽

Cited By ~ 40

Author(s):

Herbert C. Brown ◽

Nelson R. Eldred

Keyword(s):

Alkyl Halides ◽

Steric Effects ◽

Displacement Reactions

Download Full-text