The Configurational Correlation of Optically Active Biphenyls with Centrally Asymmetric Compounds. The Absolute Configuration of 6,6'-Dinitro-2,2'-diphenic Acid1

1958 ◽  
Vol 80 (2) ◽  
pp. 465-473 ◽  
Author(s):  
Paul Newman ◽  
Philip Rutkin ◽  
Kurt Mislow
Keyword(s):  
Absolute Configuration ◽  
Optically Active ◽  
Configurational Correlation ◽  
The Absolute

Isolation, structure, and synthesis of chenopodanol and the absolute configuration of chenopodene and chenopodanol

1997 ◽  
Vol 75 (6) ◽  
pp. 634-640 ◽  
Author(s):  
Motoo Tori ◽  
Tomonobu Hamaguchi ◽  
Mamiko Aoki ◽  
Masakazu Sono ◽  
Yoshinori Asakawa
Keyword(s):  
Total Synthesis ◽  
Absolute Configuration ◽  
Active Form ◽  
Optically Active ◽  
Spectroscopic Techniques ◽  
The Absolute

(−)-Chenopodanol (2) has been isolated from the liverwort Marchantiachenopoda and its structure determined by spectroscopic techniques as well as by total synthesis. Chenopodene (1) has also been synthesized in an optically active form, resulting in revision of the originally assigned absolute configuration. Keywords: chenopodanol, chenopodene, liverwort, Marchantiachenopoda, sesquiterpene.

The optically active 3-ferrocenylalanine and its application in peptide chemistry

1980 ◽  
Vol 45 (2) ◽  
pp. 435-441 ◽  
Author(s):  
Jan Pospíšek ◽  
Štefan Toma ◽  
Ivo Frič ◽  
Karel Bláha
Keyword(s):  
Circular Dichroism ◽  
Aspartic Acid ◽  
Peptide Synthesis ◽  
Absolute Configuration ◽  
Optically Active ◽  
Circular Dichroism Spectra ◽  
Peptide Chemistry ◽  
Conventional Methods ◽  
The Absolute ◽  
Circular Dichroïsm

Racemic 3-ferrocenylalanine was resolved in enantiomers using brucine. The absolute configuration was estimated by ozonolytic degradation of the N-trifluoroacetyl derivative of the (-)-enantiomer yielding D-aspartic acid. Diastereoisomeric cyclo(D-ferrocenylalanyl-L-prolyl) and cyclo-(L-3-ferrocenylalanyl-L-prolyl) were synthesized using conventional methods of peptide synthesis. Circular dichroism spectra of these cyclodipeptides are discussed and compared with spectra of the corresponding diastereoisomeric cyclodipeptides containing phenylalanine.

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