A GENERAL METHOD FOR ESTABLISHING THE ABSOLUTE CONFIGURATION OF OPTICALLY ACTIVE BIPHENYLS BY ASYMMETRIC SYNTHESIS

Kurt Mislow; Paul Newman

doi:10.1021/ja01564a072

A GENERAL METHOD FOR ESTABLISHING THE ABSOLUTE CONFIGURATION OF OPTICALLY ACTIVE BIPHENYLS BY ASYMMETRIC SYNTHESIS

Journal of the American Chemical Society ◽

10.1021/ja01564a072 ◽

1957 ◽

Vol 79 (7) ◽

pp. 1769-1769 ◽

Cited By ~ 4

Author(s):

Kurt Mislow ◽

Paul Newman

Keyword(s):

Asymmetric Synthesis ◽

Absolute Configuration ◽

Optically Active ◽

The Absolute ◽

General Method

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ChemInform Abstract: STEREOCHEMICAL STUDIES PART 24, ASYMMETRIC SYNTHESIS OF OPTICALLY ACTIVE (+)-4-METHYL-4-PHENYL-2-CYCLOHEXENONE WITH ENAMINE ALKYLATION USING PROLINE DERIVATIVES PART 25, THE ABSOLUTE CONFIGURATION AND OPTICAL PURITY OF (+)-4-METHYL-4-

Chemischer Informationsdienst ◽

10.1002/chin.197405222 ◽

1974 ◽

Vol 5 (5) ◽

pp. no-no

Author(s):

G. OTANI ◽

Y. YAMADA

Keyword(s):

Asymmetric Synthesis ◽

Absolute Configuration ◽

Optical Purity ◽

Optically Active ◽

The Absolute ◽

Proline Derivatives

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ChemInform Abstract: Prediction of the Absolute Configuration of Optically Active Pheromones Using Liquid Crystals

ChemInform ◽

10.1002/chin.199331274 ◽

2010 ◽

Vol 24 (31) ◽

pp. no-no

Author(s):

T. IKEMOTO ◽

K. MITSUHASHI ◽

K. MORI

Keyword(s):

Liquid Crystals ◽

Absolute Configuration ◽

Optically Active ◽

The Absolute

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ChemInform Abstract: Asymmetric Synthesis of 5,5-Disubstituted Thiotetronic Acids Using an Allyl Xanthate to Dithiocarbonate Rearrangement: Total Synthesis of ( 5S)-Thiolactomycin with Revision of the Absolute Configuration of the Natural Product.

ChemInform ◽

10.1002/chin.199729101 ◽

2010 ◽

Vol 28 (29) ◽

pp. no-no

Author(s):

M. S. CHAMBERS ◽

E. J. THOMAS

Keyword(s):

Total Synthesis ◽

Asymmetric Synthesis ◽

Natural Product ◽

Absolute Configuration ◽

The Absolute

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Nuclear magnetic resonance spectroscopy in optically active solvents. V. The determination of the absolute configuration of (+)-α-hydroxy-α-trifluoromethylphenylacetic acid

Tetrahedron Letters ◽

10.1016/s0040-4039(00)89701-4 ◽

1968 ◽

Vol 9 (21) ◽

pp. 2579-2582 ◽

Cited By ~ 16

Author(s):

W.H. Pirkle ◽

S.D. Beare

Keyword(s):

Nuclear Magnetic Resonance ◽

Magnetic Resonance ◽

Magnetic Resonance Spectroscopy ◽

Nuclear Magnetic Resonance Spectroscopy ◽

Absolute Configuration ◽

Optically Active ◽

Resonance Spectroscopy ◽

The Absolute ◽

Nuclear Magnetic

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Asymmetric syntheses. Part VIII. Asymmetric synthesis of β-allenic alcohols with the lithium aluminium hydride–3-O-benzyl-1,2-O-cyclohexylidene-α-D-glucofuranose complex; determination of the absolute configuration of marasin (nona-3,4-diene-6,8-diyn-1-ol) and 9-methylmarasin (deca-3,4-diene-6,8-diyn-1-ol)

Journal of the Chemical Society Perkin Transactions 1 ◽

10.1039/p19740000557 ◽

1974 ◽

pp. 557-561 ◽

Cited By ~ 8

Author(s):

Stephen R. Landor ◽

Brian J. Miller ◽

John P. Regan ◽

Austin R. Tatchell

Keyword(s):

Asymmetric Synthesis ◽

Absolute Configuration ◽

Lithium Aluminium Hydride ◽

Asymmetric Syntheses ◽

Lithium Aluminium ◽

The Absolute

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Total synthesis of (W) maculalactone A, maculalactone B and maculalactone C and the determination of the absolute configuration of natural (+) maculalactone A by asymmetric synthesis

Tetrahedron ◽

10.1016/s0040-4020(04)00621-0 ◽

2004 ◽

Author(s):

G BROWN

Keyword(s):

Total Synthesis ◽

Asymmetric Synthesis ◽

Absolute Configuration ◽

The Absolute

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ChemInform Abstract: Asymmetric Synthesis and Determination of the Absolute Configuration of FK584, an Agent for the Treatment of Overactive Detrusor.

ChemInform ◽

10.1002/chin.200120078 ◽

2001 ◽

Vol 32 (20) ◽

pp. no-no

Author(s):

Kazuhiko Take ◽

Kazuo Okumura ◽

Kazunori Tsubaki ◽

Kiyoshi Taniguchi ◽

Youichi Shiokawa

Keyword(s):

Asymmetric Synthesis ◽

Absolute Configuration ◽

Overactive Detrusor ◽

The Absolute

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ChemInform Abstract: OPTICALLY ACTIVE, AROMATIC SPIRANES, 5. STEREOCHEMISTRY OF METALLOCENES, 39. A UNIVERSAL METHOD FOR THE PREPARATION, AND DETERMINATION OF THE ABSOLUTE CONFIGURATION AND ENANTIOMERIC PURITY OF CHIRAL 2,2′-SPIROBIINDANES

Chemischer Informationsdienst ◽

10.1002/chin.197725219 ◽

1977 ◽

Vol 8 (25) ◽

pp. no-no

Author(s):

A. MEYER ◽

H. NEUDECK ◽

K. SCHLOEGL

Keyword(s):

Absolute Configuration ◽

Enantiomeric Purity ◽

Optically Active ◽

Universal Method ◽

The Absolute

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ChemInform Abstract: BOND FIXATION IN ANNULENES. 9. EQUALIZATION OF RING INVERSION AND BOND SHIFTING ENERGETICS IN 1,2,3,4-TETRAMETHYLCYCLOOCTATETRAENE. ASYMMETRIC SYNTHESIS DIRECT RESOLUTION, AND ABSOLUTE CONFIGURATION OF THE OPTICALLY ACTIVE HYDROCARBON

Chemischer Informationsdienst ◽

10.1002/chin.198043144 ◽

1980 ◽

Vol 11 (43) ◽

Author(s):

L. A. PAQUETTE ◽

J. M. GARDLIK ◽

L. K. JOHNSON ◽

K. J. MCCULLOUGH

Keyword(s):

Asymmetric Synthesis ◽

Absolute Configuration ◽

Optically Active ◽

Ring Inversion

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Isolation, structure, and synthesis of chenopodanol and the absolute configuration of chenopodene and chenopodanol

Canadian Journal of Chemistry ◽

10.1139/v97-077 ◽

1997 ◽

Vol 75 (6) ◽

pp. 634-640 ◽

Cited By ~ 11

Author(s):

Motoo Tori ◽

Tomonobu Hamaguchi ◽

Mamiko Aoki ◽

Masakazu Sono ◽

Yoshinori Asakawa

Keyword(s):

Total Synthesis ◽

Absolute Configuration ◽

Active Form ◽

Optically Active ◽

Spectroscopic Techniques ◽

The Absolute

(−)-Chenopodanol (2) has been isolated from the liverwort Marchantiachenopoda and its structure determined by spectroscopic techniques as well as by total synthesis. Chenopodene (1) has also been synthesized in an optically active form, resulting in revision of the originally assigned absolute configuration. Keywords: chenopodanol, chenopodene, liverwort, Marchantiachenopoda, sesquiterpene.

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