Relative Rates and Isomer Distributions in the Acetylation of the Methylbenzenes by Acetyl Chloride-Aluminum Chloride in Ethylene Dichloride Solution1

1959 ◽  
Vol 81 (22) ◽  
pp. 5929-5933 ◽  
Author(s):  
Gianlorenzo Marino ◽  
Herbert C. Brown
Keyword(s):  
Aluminum Chloride ◽  
Acetyl Chloride ◽  
Ethylene Dichloride

The system aluminum chloride-acetyl chloride in sulfur dioxide solvent

1982 ◽  
Vol 47 (6) ◽  
pp. 1005-1007 ◽  
Author(s):  
Boris Glavincevski ◽  
Sydney Brownstein
Keyword(s):  
Sulfur Dioxide ◽  
Aluminum Chloride ◽  
Acetyl Chloride

Acetylation and Formylation of 3-Ferrocenylpyrroles

1999 ◽  
Vol 64 (1) ◽  
pp. 99-106
Author(s):  
Battsengel Gotov ◽  
Štefan Toma ◽  
Eva Solčániová
Keyword(s):  
Acetic Acid ◽  
Acetic Anhydride ◽  
Aluminum Chloride ◽  
Acetyl Chloride ◽  
Trifluoroacetic Anhydride ◽  
Acid Mixture ◽  
Chloride Method

Acetylations of 3-ferrocenyl-1-methylpyrrole as well as 3-cyano-4-ferrocenylpyrrole and 3-cyano-4-ferrocenyl-1-methylpyrrole were performed. The course of the acylation is highly dependent on the acylation agent, that is acetyl chloride/aluminum chloride (method A), trifluoroacetic anhydride-acetic acid mixture (method B) or acetic anhydride/Sc(OTf)3 (method C). Method A gives the acetylation on ferrocene moiety, method B affords the trifluoroacetylation on pyrrole moiety and method C affords pyrrole moiety acetylation. Vielsmeier-Haack formylation gives the products of substitution on pyrrole moiety.

REACTIONS OF (i) ALUMINUM TERTIARY BUTOXIDE WITH ACETYL CHLORIDE AND (ii) ALUMINUM CHLORIDE WITH TERTIARY BUTYL ACETATE

1964 ◽  
Vol 42 (4) ◽  
pp. 717-723 ◽  
Author(s):  
R. C. Mehrotra ◽  
R. A. Misra
Keyword(s):  
Aluminum Chloride ◽  
Butyl Acetate ◽  
Acetyl Chloride ◽  
Tertiary Butyl ◽  
Plausible Mechanism

The reactions between aluminum tertiary butoxide and acetyl chloride have been studied. The addition of 1 mole of acetyl chloride to aluminum tertiary butoxide forms monochloride ditertiary butoxide, which, with another mole of acetyl chloride, appears to give the dichloride monotertiary butoxide derivatives. Further, these products appear to react with tertiary butyl acetate formed in the reaction itself, giving acetate derivatives. The above is confirmed by a detailed study of the reactions between aluminum chloride and tertiary butyl acetate, which have been found to result in the acetate derivatives. A plausible mechanism has been suggested.

Fragmentation-acetylation of isooctane with acetyl chloride-aluminum chloride complex

1969 ◽  
Vol 10 (30) ◽  
pp. 2581-2584 ◽  
Author(s):  
I. Tabushi ◽  
K. Fujita ◽  
R. Oda ◽  
M. Tsuboi
Keyword(s):  
Aluminum Chloride ◽  
Acetyl Chloride ◽  
Chloride Complex
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