REACTIONS OF (i) ALUMINUM TERTIARY BUTOXIDE WITH ACETYL CHLORIDE AND (ii) ALUMINUM CHLORIDE WITH TERTIARY BUTYL ACETATE

1964 ◽  
Vol 42 (4) ◽  
pp. 717-723 ◽  
Author(s):  
R. C. Mehrotra ◽  
R. A. Misra
Keyword(s):  
Aluminum Chloride ◽  
Butyl Acetate ◽  
Acetyl Chloride ◽  
Tertiary Butyl ◽  
Plausible Mechanism

The reactions between aluminum tertiary butoxide and acetyl chloride have been studied. The addition of 1 mole of acetyl chloride to aluminum tertiary butoxide forms monochloride ditertiary butoxide, which, with another mole of acetyl chloride, appears to give the dichloride monotertiary butoxide derivatives. Further, these products appear to react with tertiary butyl acetate formed in the reaction itself, giving acetate derivatives. The above is confirmed by a detailed study of the reactions between aluminum chloride and tertiary butyl acetate, which have been found to result in the acetate derivatives. A plausible mechanism has been suggested.

The system aluminum chloride-acetyl chloride in sulfur dioxide solvent

1982 ◽  
Vol 47 (6) ◽  
pp. 1005-1007 ◽  
Author(s):  
Boris Glavincevski ◽  
Sydney Brownstein
Keyword(s):  
Sulfur Dioxide ◽  
Aluminum Chloride ◽  
Acetyl Chloride

Acetylation and Formylation of 3-Ferrocenylpyrroles

1999 ◽  
Vol 64 (1) ◽  
pp. 99-106
Author(s):  
Battsengel Gotov ◽  
Štefan Toma ◽  
Eva Solčániová
Keyword(s):  
Acetic Acid ◽  
Acetic Anhydride ◽  
Aluminum Chloride ◽  
Acetyl Chloride ◽  
Trifluoroacetic Anhydride ◽  
Acid Mixture ◽  
Chloride Method

Acetylations of 3-ferrocenyl-1-methylpyrrole as well as 3-cyano-4-ferrocenylpyrrole and 3-cyano-4-ferrocenyl-1-methylpyrrole were performed. The course of the acylation is highly dependent on the acylation agent, that is acetyl chloride/aluminum chloride (method A), trifluoroacetic anhydride-acetic acid mixture (method B) or acetic anhydride/Sc(OTf)3 (method C). Method A gives the acetylation on ferrocene moiety, method B affords the trifluoroacetylation on pyrrole moiety and method C affords pyrrole moiety acetylation. Vielsmeier-Haack formylation gives the products of substitution on pyrrole moiety.

Comparative Toxicity of Dexamethasone and its Tertiary Butyl Acetate Ester After Topical Ocular Instillation in Rabbits

1973 ◽  
Vol 76 (1) ◽  
pp. 117-125 ◽  
Author(s):  
Thomas O. McDonald ◽  
Katherine Kasten ◽  
Ronald Hervey ◽  
Stennis Gregg ◽  
Danna Smith ◽  
...  
Keyword(s):  
Butyl Acetate ◽  
Tertiary Butyl ◽  
Acetate Ester ◽  
Comparative Toxicity

scholarly journals Solvent Deuterium Isotope Effects on Acid-Base Reactions. Part IV. Lyonium Ion-Catalyzed Hydrolysis of Tertiary Butyl Acetate in Isotopically Different Waters.

1969 ◽  
Vol 23 ◽  
pp. 713-714
Author(s):  
Pentti Salomaa ◽  
Martti Ketola ◽  
Charles Larsen ◽  
Per Halfdan Nielsen ◽  
Alf A. Lindberg ◽  
...  
Keyword(s):  
Butyl Acetate ◽  
Isotope Effects ◽  
Acid Base ◽  
Tertiary Butyl ◽  
Deuterium Isotope Effects ◽  
Hydrolysis Of

Determination of Certain VOCs in Paints and Architectural Coatings by Dynamic Headspace Gas Chromatography-Mass Spectrometry

2021 ◽  
Author(s):  
Nicholas Alderman ◽  
Matthew Courville ◽  
Ryszard Tokarcyzk
Keyword(s):  
Methyl Acetate ◽  
Butyl Acetate ◽  
Dimethyl Carbonate ◽  
Gas Chromatography Mass Spectrometry ◽  
Headspace Gas Chromatography ◽  
Dynamic Headspace ◽  
Tertiary Butyl ◽  
Headspace Gas ◽  
Architectural Coatings

A quantitative method for the determination of the following VOCs: acetone, dichloromethane, dimethyl carbonate, methyl acetate, tertiary butyl acetate, chlorobenzotrifluoride (4-CBTF) and propylene carbonate in paints was developed in support...

scholarly journals Subchronic, reproductive, and maternal toxicity studies with tertiary butyl acetate (TBAC)

2014 ◽  
Vol 68 (3) ◽  
pp. 332-342 ◽  
Author(s):  
Willem Faber ◽  
Daniel Kirkpatrick ◽  
Pragati Coder ◽  
Abby Li ◽  
Susan Borghoff ◽  
...  
Keyword(s):  
Butyl Acetate ◽  
Tertiary Butyl ◽  
Toxicity Studies
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