Rates of Reaction of Benzoyl Chloride with Representative Aromatic Hydrocarbons in Ethylene Dichloride Solution under the Influence of Aluminum Chloride. Partial Rate Factors for the Benzoylation Reaction1

1959 ◽  
Vol 81 (13) ◽  
pp. 3308-3310 ◽  
Author(s):  
Herbert C. Brown ◽  
Gianlorenzo Marino
1981 ◽  
Vol 59 (2) ◽  
pp. 227-231 ◽  
Author(s):  
Peter David Clark ◽  
David M. McKinnon

Naphtho[2,1-b]thiophene undergoes addition of aromatic hydrocarbons across the 1,2-bond in the presence of aluminum chloride. At 20 °C 1-aryl-1,2-dihydronaphtho[2,1-b]thiophenes are the major products and at higher temperatures 2-arylnaphtho[2,1-b]thiophenes result. 1-Arylnaphtho[2,1-b]thiophenes may be prepared by treatment of the dihydro-addition products with 2,3-dichloro-5,6-dicyano-1,4-benzoquinone thus giving a new synthesis of 1- and 2-arylnaphtho[2,1-b]thiophenes from the parent heterocycle.


1976 ◽  
Vol 49 (1) ◽  
pp. 260-264 ◽  
Author(s):  
Isao Mochida ◽  
Noriyoshi Fukuda ◽  
Keiko Maeda ◽  
Kenjiro Takeshita

Sign in / Sign up

Export Citation Format

Share Document