Functional Analogue Reaction Systems of the DMSO Reductase Isoenzyme Family:  Probable Mechanism ofS-Oxide Reduction in Oxo Transfer Reactions Mediated by Bis(dithiolene)−Tungsten(IV,VI) Complexes

2002 ◽  
Vol 124 (16) ◽  
pp. 4312-4320 ◽  
Author(s):  
Kie-Moon Sung ◽  
R. H. Holm
Keyword(s):  
Probable Mechanism ◽  
Transfer Reactions ◽  
Oxide Reduction ◽  
Dmso Reductase ◽  
Reaction Systems ◽  
Oxo Transfer

Chemistry of oxidomolybdenum(IV) and -(VI) complexes with ONS donor ligands: Synthesis, computational evaluation and oxo-transfer reactions

Polyhedron ◽  
2018 ◽  
Vol 141 ◽  
pp. 322-336 ◽  
Author(s):  
Saswati ◽  
Satabdi Roy ◽  
Subhashree P. Dash ◽  
Rama Acharyya ◽  
Werner Kaminsky ◽  
...  
Keyword(s):  
Transfer Reactions ◽  
Donor Ligands ◽  
Computational Evaluation ◽  
Oxo Transfer

scholarly journals Catalytic consequences of open and closed grafted Al(III)-calix[4]arene complexes for hydride and oxo transfer reactions

2013 ◽  
Vol 110 (7) ◽  
pp. 2484-2489 ◽  
Author(s):  
P. Nandi ◽  
W. Tang ◽  
A. Okrut ◽  
X. Kong ◽  
S.-J. Hwang ◽  
...  
Keyword(s):  
Transfer Reactions ◽  
Arene Complexes ◽  
Oxo Transfer

scholarly journals Quantitation of the ligand effect in oxo-transfer reactions of dioxo-Mo(vi) trispyrazolyl borate complexes

2013 ◽  
Vol 42 (9) ◽  
pp. 3071-3081 ◽  
Author(s):  
Partha Basu ◽  
Brian W. Kail ◽  
Andrew K. Adams ◽  
Victor N. Nemykin
Keyword(s):  
Transfer Reactions ◽  
Ligand Effect ◽  
Borate Complexes ◽  
Oxo Transfer

scholarly journals Effect of high pressure on the topography of potential energy surfaces

2016 ◽  
Vol 94 (12) ◽  
pp. 1057-1064 ◽  
Author(s):  
Jacob Spooner ◽  
Brandon Smith ◽  
Noham Weinberg
Keyword(s):  
High Pressure ◽  
Potential Energy ◽  
Potential Energy Surfaces ◽  
Chemical Compounds ◽  
Transfer Reactions ◽  
Reaction Systems ◽  
Elevated Pressures ◽  
Chemical Effects ◽  
Condensed Phase Reactions ◽  
Energy Surfaces

Properties and reactivity of chemical compounds change dramatically at elevated pressures. Since kinetics and mechanisms of condensed-phase reactions are described in terms of their potential energy (PESs) or Gibbs energy (GESs) surfaces, chemical effects of high pressure can be assessed through analysis of pressure-induced deformations of GESs of solvated reaction systems. We discuss general trends expected for such changes and use quantum mechanical calculations to construct PESs of compressed species for hydrogen and methyl transfer reactions.

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