scholarly journals Quantitation of the ligand effect in oxo-transfer reactions of dioxo-Mo(vi) trispyrazolyl borate complexes

2013 ◽  
Vol 42 (9) ◽  
pp. 3071-3081 ◽  
Author(s):  
Partha Basu ◽  
Brian W. Kail ◽  
Andrew K. Adams ◽  
Victor N. Nemykin
Keyword(s):  
Transfer Reactions ◽  
Ligand Effect ◽  
Borate Complexes ◽  
Oxo Transfer

Hydrogen Atom Transfer Rates from Tp-Containing Metal Hydrides to Trityl Radicals

2020 ◽  
Author(s):  
Hunter B. Vibbert ◽  
Hagen Neugebauer ◽  
Jack R Norton ◽  
Andreas Hansen ◽  
Markus Bursch ◽  
...  
Keyword(s):  
Hydrogen Atom ◽  
Rate Constants ◽  
Transfer Rate ◽  
Metal Hydrides ◽  
Hydrogen Atom Transfer ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Transfer Rates ◽  
Borate Complexes ◽  
And Tungsten

The H• transfer rate constants for a series of group 6 molybdenum and tungsten pyrazolyl borate complexes are described. The rate constants for these complexes were found to span a range over 1 magnitude. Analysis of the H• transfer rate constants suggests that a combination of steric, electronic, and enthalpic factors are important in these reactions. Further analysis of the components suggests that the generated 17 e– radicals of these complexes are less electrophilic than the more commonly used CpCr(CO)3H complexes. General implications for H• transfer reactions are discussed.

Chemistry of oxidomolybdenum(IV) and -(VI) complexes with ONS donor ligands: Synthesis, computational evaluation and oxo-transfer reactions

Polyhedron ◽  
2018 ◽  
Vol 141 ◽  
pp. 322-336 ◽  
Author(s):  
Saswati ◽  
Satabdi Roy ◽  
Subhashree P. Dash ◽  
Rama Acharyya ◽  
Werner Kaminsky ◽  
...  
Keyword(s):  
Transfer Reactions ◽  
Donor Ligands ◽  
Computational Evaluation ◽  
Oxo Transfer

scholarly journals Catalytic consequences of open and closed grafted Al(III)-calix[4]arene complexes for hydride and oxo transfer reactions

2013 ◽  
Vol 110 (7) ◽  
pp. 2484-2489 ◽  
Author(s):  
P. Nandi ◽  
W. Tang ◽  
A. Okrut ◽  
X. Kong ◽  
S.-J. Hwang ◽  
...  
Keyword(s):  
Transfer Reactions ◽  
Arene Complexes ◽  
Oxo Transfer

Structural and Mechanistic Studies of Oxo-Transfer Reactions of Bis(arylimido)oxorhenium(VII)

2001 ◽  
Vol 20 (1) ◽  
pp. 148-156 ◽  
Author(s):  
Wei-Dong Wang ◽  
Ilia A. Guzei ◽  
James H. Espenson
Keyword(s):  
Transfer Reactions ◽  
Mechanistic Studies ◽  
Oxo Transfer

Bimetallic Reactivity. Oxo Transfer Reactions with a Heterobimetallic Complex of Iron(II) and Vanadium(III)

1997 ◽  
Vol 36 (10) ◽  
pp. 2230-2235 ◽  
Author(s):  
David G. McCollum ◽  
Glenn P. A. Yap ◽  
Louise Liable-Sands ◽  
Arnold L. Rheingold ◽  
B. Bosnich
Keyword(s):  
Transfer Reactions ◽  
Heterobimetallic Complex ◽  
Oxo Transfer
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