The Spectrophotometric Determination of the Rate Constant of First Order Reactions1

1952 ◽  
Vol 74 (2) ◽  
pp. 563-563 ◽  
Author(s):  
Edward L. King
Keyword(s):  
Spectrophotometric Determination ◽  
Rate Constant ◽  
First Order

Vulcameter Determination of Best Cure

1965 ◽  
Vol 38 (4) ◽  
pp. 757-768 ◽  
Author(s):  
S. D. Gehman ◽  
F. S. Maxey ◽  
S. R. Ogilby
Keyword(s):  
Rate Constant ◽  
Work Load ◽  
Service Performance ◽  
Stress Strain ◽  
First Order ◽  
Testing Laboratories ◽  
Physical Testing ◽  
Strain Testing ◽  
Minimum Number

Abstract Using a continuous cure curve to select a minimum number of stepped cures, it should be possible to vulcanize and test fewer sheets to determine best cure. This procedure is attractive for its potential of expediting the output of physical testing laboratories and especially for reducing the work load of stress-strain testing. Cure curves recorded with the Vulcameter approximated first-order reactions. Equations were derived to calculate the final force and rate constant from recorded force values without carrying the reaction to completion. A chart is suggested to assist in calculating the rate constant. Time for a given fractional rise in force depends only on the rate constant so that a chart for obtaining it is relatively simple. Experience and correlation with service performance in selecting best cures is emphasized. 95% rise times from Vulcameter curves were compared with conventionally selected best cures for a wide variety of compounds. Indications are that experience with the method might reduce the number of test-sheet cures to determine optimum stress-strain properties to one, two, or three depending upon the compound and the exactness required.

scholarly journals Derivative spectrophotometric determination of acetamiprid in the presence of 6-chloronicotinic acid

2012 ◽  
Vol 77 (7) ◽  
pp. 911-917 ◽  
Author(s):  
Valéria Guzsvány ◽  
Sanja Lazic ◽  
Natasa Vidakovic ◽  
Zsigmond Papp
Keyword(s):  
Simultaneous Determination ◽  
Spectrophotometric Determination ◽  
Spectrophotometric Method ◽  
Detection Limits ◽  
Model Systems ◽  
Order Derivative ◽  
Zero Crossing ◽  
First Order ◽  
Relative Standard

A simple first-order derivative spectrophotometric method was developed for the simultaneous determination of acetamiprid and 6-chloronicotinic acid (6-CNA) at pH 7.0. By using the zero-crossing approach, acetamiprid was determined at 269.0 nm and 6-CNA at 216.0 nm with the detection limits of 7.19x10-7 and 8.25x10-7 mol dm-3, respectively and relative standard deviations not exceeding 1.2% in the case of model systems.

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