Relative Reactivities of Organic Halides in Displacement Reactions. I. Allylic Chlorides

1953 ◽  
Vol 75 (11) ◽  
pp. 2724-2725 ◽  
Author(s):  
Shigeru Oae ◽  
Calvin A. VanderWerf
Keyword(s):  
Organic Halides ◽  
Displacement Reactions

On the displacement reactions of organic substances in water

2005 ◽  
Vol 83 (9) ◽  
pp. 1667-1719 ◽  
Author(s):  
J MW Scott
Keyword(s):  
Free Energy ◽  
Temperature Dependence ◽  
Isotope Effects ◽  
Linear Free Energy Relationship ◽  
Linear Free Energy Relationships ◽  
Organic Substances ◽  
Linear Free Energy ◽  
Organic Halides ◽  
Displacement Reactions ◽  
Energy Relationships

The hydrolyses of a series of organic halides, nitrates, sulphonates, and perchlorates are examined from the standpoint of thermodynamics, kinetics, temperature dependence, isotope effects, the Kurz equation, and the Guthrie linear free energy relationship. The thermodynamics of several definite bimolecular displacements are also examined. Some mechanistic revisions are suggested to reach an improved accommodation with the experimental observations.Key words: kinetics, thermodynamics, hydrolytic displacements, mechanism, ionic displacements, nucleofugality, linear free energy relationships.

Oxidative transformation of alcohols and organic halides in aqueous solution

2014 ◽  
Vol 38 (8) ◽  
pp. 3749-3754 ◽  
Author(s):  
Neeraj Gupta ◽  
Apoorva Thakur ◽  
Pushpa Bhardwaj
Keyword(s):  
Aqueous Solution ◽  
Oxidative Transformation ◽  
Organic Halides ◽  
Oxidation Of Alcohols

Using water as the only solvent for the oxidation of alcohols and organic halides, a complete solventless process for the preparation of water immiscible aldehydes has been developed.

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