Phosphorus- and Arsenic-Bridged Complexes of Metal Carbonyls. IV.1Reactions of Tetrakis(trifluoromethyl)diarsine with Some Metal Carbonyl Compounds

1964 ◽  
Vol 86 (6) ◽  
pp. 1030-1032 ◽  
Author(s):  
W. R. Cullen ◽  
R. G. Hayter
Keyword(s):  
Carbonyl Compounds ◽  
Metal Carbonyl ◽  
Metal Carbonyls

Fixierung von Metallcarbonylen auf Poly-Isocyaniden [1] / Anchoring of Metal Carbonyls on Poly Isocyanides [1]

1982 ◽  
Vol 37 (2) ◽  
pp. 201-208 ◽  
Author(s):  
Hartmut Menzel ◽  
Wolf Peter Fehlhammer ◽  
Wolfgang Beck
Keyword(s):  
Carbonyl Compounds ◽  
Metal Carbonyl ◽  
Metal Carbonyls ◽  
Cyano Complexes ◽  
Polymeric Supports

Abstract Polyisocyanides with the groups -CH2N ≡ C and -C(O)O(CH2)2N≡C attached to polystyrene have been prepared and reacted with various metal carbonyl compounds resulting in the fixation on the polymeric supports of-M(CO)5, -M(CO)4 (M = Cr, Mo, W), -MO(Cl)(η-C5H5)(CO)2, -Mn2(CO)η -Mn(CO)ηX (N = 3, 4; X = Cl, Br), -Fe(CO)4, -Fe3(CO)11, -FeI2(CO)2, -FeX(η-C5H5)(CO) (X = Cl, Br, I), -Ru(CO)4, -Ru3(CO)9, ,,-Os3H2(CO)10", and -RhCl(CO)2. The cyano complexes [Fe(CN)2(η-C5H5)CO]- and [Mo(CN)2(η-C5H5)(CO)2]- have been immobilized by alkylation with chloromethylated polystyrene

Reaktionen von Metallcarbonylen mit Diazirin / Reactions of Metal Carbonyls with Diazirine

1975 ◽  
Vol 30 (9-10) ◽  
pp. 716-719 ◽  
Author(s):  
Wolfgang Beck ◽  
Wolfgang Danzer
Keyword(s):  
Carbonyl Compounds ◽  
Metal Carbonyl ◽  
Metal Carbonyls

Pentamethylendiazirine (N͡=N) has been found in metal carbonyl compounds as a monodentate two electron ligand (π-CH3C5Η4Mn(CO)2 N͡=N, (OC)5W N͡=N) or as a bidentate four electron ligand ((OC4M (N͡=N)2M(CO)4 (M = Mo, W), (OC)4Fe N͡=N Fe(CO)4). The reaction of Fe2(CO9 with diazirine affords the isocyanate and/or methylenamino-bridged complexes (OC)3Fe(NCO) (N=C< )Fe(CO)3 and (OC)3Fe (N=C< )2Fe(CO)3.

Study of the CO stretching frequencies and intensities in metal-carbonyl compounds

1982 ◽  
Vol 82 (1-2) ◽  
pp. 43-50 ◽  
Author(s):  
M. van Rentergem ◽  
E.G. Claeys ◽  
G.P. van der Kelen
Keyword(s):  
Carbonyl Compounds ◽  
Metal Carbonyl
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