Intermediacy of metal-olefin complexes in cycloaddition and insertion reactions at transition metal-.eta.1-allyl bonds

1974 ◽  
Vol 96 (17) ◽  
pp. 5655-5656 ◽  
Author(s):  
Loomis S. Chen ◽  
Sophia R. Su ◽  
Andrew Wojcicki
Keyword(s):  
Transition Metal ◽  
Insertion Reactions

Chiral proton-transfer shuttle catalysts for carbene insertion reactions

2018 ◽  
Vol 16 (17) ◽  
pp. 3087-3094 ◽  
Author(s):  
Yuan-Yuan Ren ◽  
Shou-Fei Zhu ◽  
Qi-Lin Zhou
Keyword(s):  
Transition Metal ◽  
Proton Transfer ◽  
Insertion Reactions ◽  
Carbene Insertion ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

The development of chiral proton-transfer shuttles provides a totally new enantiocontrol strategy for transition metal-catalyzed asymmetric carbene insertion reactions.

A New Route to Coordination Complexes of Nitroxyl (HNO) via Insertion Reactions of Nitrosonium Triflate with Transition-Metal Hydrides

2002 ◽  
Vol 124 (41) ◽  
pp. 12068-12069 ◽  
Author(s):  
Rory Melenkivitz ◽  
Joel S. Southern ◽  
Gregory L. Hillhouse ◽  
Thomas E. Concolino ◽  
Louise M. Liable-Sands ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Coordination Complexes ◽  
Insertion Reactions ◽  
Transition Metal Hydrides

Insertion reactions of N-sulfinyl sulfonamides and sulfur bis(sulfonylimides) into transition-metal-carbon .sigma. bonds

1986 ◽  
Vol 5 (2) ◽  
pp. 366-374 ◽  
Author(s):  
Tak Wai. Leung ◽  
Gary G. Christoph ◽  
Judith. Gallucci ◽  
Andrew. Wojcicki
Keyword(s):  
Transition Metal ◽  
Insertion Reactions ◽  
Sigma Bonds
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