A New Route to Coordination Complexes of Nitroxyl (HNO) via Insertion Reactions of Nitrosonium Triflate with Transition-Metal Hydrides

2002 ◽  
Vol 124 (41) ◽  
pp. 12068-12069 ◽  
Author(s):  
Rory Melenkivitz ◽  
Joel S. Southern ◽  
Gregory L. Hillhouse ◽  
Thomas E. Concolino ◽  
Louise M. Liable-Sands ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Coordination Complexes ◽  
Insertion Reactions ◽  
Transition Metal Hydrides

Evidence for the radical pair mechanism in ‘insertion’ reactions of transition metal hydrides with conjugated dienes

1986 ◽  
Vol 0 (4) ◽  
pp. 312-314 ◽  
Author(s):  
Marian J. Thomas ◽  
Thomas A. Shackleton ◽  
Steven C. Wright ◽  
Daniel J. Gillis ◽  
Johannes P. Colpa ◽  
...  
Keyword(s):  
Transition Metal ◽  
Radical Pair ◽  
Metal Hydrides ◽  
Conjugated Dienes ◽  
Radical Pair Mechanism ◽  
Insertion Reactions ◽  
Transition Metal Hydrides

scholarly journals Complex transition metal hydrides: linear correlation of countercation electronegativity versus T–D bond lengths

2015 ◽  
Vol 51 (56) ◽  
pp. 11248-11251 ◽  
Author(s):  
T. D. Humphries ◽  
D. A. Sheppard ◽  
C. E. Buckley
Keyword(s):  
Transition Metal ◽  
Bond Length ◽  
Linear Correlation ◽  
Metal Hydrides ◽  
Bond Lengths ◽  
Transition Metal Hydrides ◽  
Complex Hydrides

For homoleptic 18-electron complex hydrides, an inverse linear correlation has been established between the T–deuterium bond length and the average electronegativity of the metal countercations.

Kinetic hydricity of transition-metal hydrides toward trityl cation

1995 ◽  
Vol 14 (9) ◽  
pp. 4031-4033 ◽  
Author(s):  
Tan-Yun Cheng ◽  
R. Morris Bullock
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Transition Metal Hydrides ◽  
Trityl Cation

Positive ions of the first‐ and second‐row transition metal hydrides

1987 ◽  
Vol 87 (1) ◽  
pp. 481-492 ◽  
Author(s):  
Lars G. M. Pettersson ◽  
Charles W. Bauschlicher ◽  
Stephen R. Langhoff ◽  
Harry Partridge
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Transition Metal Hydrides ◽  
Positive Ions

The Formation and Properties of Rare-Earth and Transition Metal Hydrides

1975 ◽  
pp. 659-674 ◽  
Author(s):  
L. C. Beavis ◽  
R. S. Blewer ◽  
J. W. Guthrie ◽  
E. J. Nowak ◽  
W. G. Perkins
Keyword(s):  
Rare Earth ◽  
Transition Metal ◽  
Metal Hydrides ◽  
Transition Metal Hydrides

Addition of acrylonitrile to anionic transition metal hydrides. An ionic model for homogeneous olefin processes

1989 ◽  
Vol 30 (14) ◽  
pp. 1781-1784 ◽  
Author(s):  
Marcetta Y. Darensbourg ◽  
Barbara Floris ◽  
Kay A. Youngdahl
Keyword(s):  
Transition Metal ◽  
Metal Hydrides ◽  
Ionic Model ◽  
Transition Metal Hydrides
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