Conformational analysis of 2-alkylcyclohexanone-lanthanide chelate complexes

Kenneth L. Servis; Donald J. Bowler

doi:10.1021/ja00791a058

Conformational analysis of 2-alkylcyclohexanone-lanthanide chelate complexes

Journal of the American Chemical Society ◽

10.1021/ja00791a058 ◽

1973 ◽

Vol 95 (10) ◽

pp. 3392-3394 ◽

Cited By ~ 14

Author(s):

Kenneth L. Servis ◽

Donald J. Bowler

Keyword(s):

Conformational Analysis ◽

Chelate Complexes ◽

Lanthanide Chelate

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Conformational analysis of 2-alkylcyclohexanone-lanthanide chelate complexes

Journal of the American Chemical Society ◽

10.1021/ja00834a014 ◽

1975 ◽

Vol 97 (1) ◽

pp. 73-80 ◽

Cited By ~ 30

Author(s):

Kenneth L. Servis ◽

Donald J. Bowler ◽

Cliff Ishii

Keyword(s):

Conformational Analysis ◽

Chelate Complexes ◽

Lanthanide Chelate

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ChemInform Abstract: CONFORMATIONAL ANALYSIS OF 2-ALKYLCYCLOHEXANONE-LANTHANIDE CHELATE COMPLEXES

Chemischer Informationsdienst ◽

10.1002/chin.197513361 ◽

1975 ◽

Vol 6 (13) ◽

pp. no-no

Author(s):

KENNETH L. SERVIS ◽

DONALD J. BOWLER ◽

CLIFF ISHII

Keyword(s):

Conformational Analysis ◽

Chelate Complexes ◽

Lanthanide Chelate

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Nonempirical conformational analysis of oubaine molecule chelate complexes with Ca2+ and possible mechanism of modulation of transductor function of Na+,K+-ATPhase

Russian Journal of General Chemistry ◽

10.1134/s1070363208100150 ◽

2008 ◽

Vol 78 (10) ◽

pp. 1910-1919 ◽

Cited By ~ 2

Author(s):

I. V. Rogachevskii ◽

E. V. Lopatina ◽

V. A. Penniyainen ◽

B. V. Krylov

Keyword(s):

Conformational Analysis ◽

Chelate Complexes

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Preparation and properties of lanthanide chelate complexes

Inorganic Chemistry ◽

10.1021/ic50101a013 ◽

1971 ◽

Vol 10 (7) ◽

pp. 1383-1387 ◽

Cited By ~ 60

Author(s):

J. Selbin ◽

N. Ahmad ◽

N. Bhacca

Keyword(s):

Chelate Complexes ◽

Lanthanide Chelate

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Conformational analysis of the bidentate ligand, tetramethylmethylenediphosphine dioxide, in its chelate complexes with metals

Theoretical and Experimental Chemistry ◽

10.1007/bf00520369 ◽

1978 ◽

Vol 13 (3) ◽

pp. 256-262

Author(s):

D. G. Dashevskii ◽

A. P. Baranov ◽

T. Ya. Medved' ◽

M. I. Kabachnik

Keyword(s):

Conformational Analysis ◽

Bidentate Ligand ◽

Chelate Complexes

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Lanthanide chelate complexes of salicyloyl hydrazide-salicylaldehyde schiff base (SHSASB) and anthranilic acid-salicylaldehyde schiff base (AASASB)

Inorganica Chimica Acta ◽

10.1016/s0020-1693(00)82303-8 ◽

1985 ◽

Vol 110 (3) ◽

pp. 169-173 ◽

Cited By ~ 15

Author(s):

N.S. Navaneetham ◽

R. Kalyanasundaram ◽

S. Soundararajan

Keyword(s):

Schiff Base ◽

Anthranilic Acid ◽

Chelate Complexes ◽

Lanthanide Chelate

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Exploration of the single-stranded DNA-binding domains of the gene V proteins encoded by the filamentous bacteriophages IKe and M13 by means of spin-labeled oligonucleotide and lanthanide-chelate complexes

European Journal of Biochemistry ◽

10.1111/j.1432-1033.1993.tb18169.x ◽

1993 ◽

Vol 216 (2) ◽

pp. 507-517 ◽

Cited By ~ 8

Author(s):

John P. M. DUYNHOVEN ◽

Irene M. A. NOOREN ◽

Dorine W. SWINKELS ◽

Paul J. M. FOLKERS ◽

Ben J. M. HARMSEN ◽

...

Keyword(s):

Dna Binding ◽

Chelate Complexes ◽

Single Stranded Dna ◽

Dna Binding Domains ◽

Binding Domains ◽

Lanthanide Chelate ◽

Filamentous Bacteriophages

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The application of lanthanide chelate complexes to contrast-enhanced perfusion MR imaging of ischemic brain

Journal of Inorganic Biochemistry ◽

10.1016/0162-0134(93)85431-7 ◽

1993 ◽

Vol 51 (1-2) ◽

pp. 402

Author(s):

J. Kucharczyk ◽

S. Rocklage ◽

A. Watson

Keyword(s):

Mr Imaging ◽

Chelate Complexes ◽

Ischemic Brain ◽

Lanthanide Chelate ◽

Contrast Enhanced ◽

Perfusion Mr ◽

Perfusion Mr Imaging

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ChemInform Abstract: Lanthanide Chelate Complexes of Salicyloyl Hydrazide-Salicylaldehyde Schiff Base (SHSASB) and Anthranilic Acid

Chemischer Informationsdienst ◽

10.1002/chin.198610316 ◽

1986 ◽

Vol 17 (10) ◽

Author(s):

N. S. NAVANEETHAM ◽

R. KALYANASUNDARAM ◽

S. SOUNDARARAJAN

Keyword(s):

Schiff Base ◽

Anthranilic Acid ◽

Chelate Complexes ◽

Lanthanide Chelate

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A Quantum Chemical Conformational Analysis of the Ethylenediamine Molecule

Canadian Journal of Chemistry ◽

10.1139/v72-158 ◽

1972 ◽

Vol 50 (7) ◽

pp. 1005-1007 ◽

Cited By ~ 14

Author(s):

N. Hadjiliadis ◽

A. Diot ◽

T. Theophanides

Keyword(s):

Experimental Data ◽

Conformational Analysis ◽

Metal Complexes ◽

Calculation Method ◽

Quantum Chemical ◽

Experimental Results ◽

Chelate Complexes ◽

Trans Form ◽

Stable Conformation

The conformational analysis of the ethylenediamine molecule has been studied by the LCAO-EHMO calculation method. The results indicate that the most stable conformation of the molecule is the gauche form, in which the angle N—C—C—N is ca. 63.0° measured from the cis form. This is in agreement with experimental data and can explain the fact that the ethylenediamine in its chelate complexes is always in the gauche form. In addition, the present results indicate that the trans form is the next most stable conformation of ethylenediamine in agreement with experimental results on bridging ethylenediamine metal complexes.

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