Transition metal cyanocarbon derivatives. I. Polycyanovinyl, dicyanovinylidene, and dicyanomethylene derivatives of metal carbonyls from cyanocarbon halides and metal carbonyl anions

1973 ◽  
Vol 95 (6) ◽  
pp. 1811-1817 ◽  
Author(s):  
R. B. King ◽  
Mohan Singh. Saran
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Metal Carbonyls ◽  
Derivatives Of

scholarly journals Übergangsmetall-substituierte VB Elementsysteme, 7.

1975 ◽  
Vol 30 (3-4) ◽  
pp. 229-234 ◽  
Author(s):  
Wolfgang Malisch ◽  
Peter Panster
Keyword(s):  
Transition Metal ◽  
Mass Spectroscopy ◽  
Bond Cleavage ◽  
Metal Carbonyl ◽  
Metal Carbonyls ◽  
H Nmr ◽  
Complex Metal ◽  
Stable Species ◽  
New Compounds

The reaction of SbBr3 with the complex metal carbonyl anions [π-C5H6(CO)3M]Na (M = Mo, W) leads to the formation of transition metal antimony bromides π-C5H5(CO)3M-Sb̅-Br2, which can be further metallated, yielding the stable species [XXX]All bromine substituted transition metal stibines prove to be excellent coordinating ligands and can easily be introduced into activated metal carbonyls. The interaction of π-C5H5(CO)3M-Sb̅Br2, with bromine results in a quantitative Sb-M bond cleavage, presumably via primary formation of pentavalent intermediates. All new compounds are fully characterized by means of IR, 1H NMR and mass spectroscopy.

Transition Metal Carbonyl Derivatives of Magnesium

2007 ◽  
pp. 56-61 ◽  
Author(s):  
G. B. Mcvicker ◽  
T. J. Marks ◽  
A. M. Seyam
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Carbonyl Derivatives ◽  
Derivatives Of
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