Intramolecular rearrangement reactions of tris-chelate complexes. III. Analysis of the rearrangements of tris(.alpha.-isopropenyl- and .alpha.-isopropyltropolonato)aluminum(III) and -cobalt(III). Examples of stereochemically nonrigid aluminum(III) and cobalt(III) complexes

1972 ◽  
Vol 94 (18) ◽  
pp. 6411-6426 ◽  
Author(s):  
S. S. Eaton ◽  
J. R. Hutchison ◽  
R. H. Holm ◽  
E. L. Muetterties
Keyword(s):  
Intramolecular Rearrangement ◽  
Chelate Complexes ◽  
Rearrangement Reactions

Umlagerungsreaktionen von lithiierten Silylhydroxylaminen mit Fluorsilanen / Rearrangement Reactions of Lithiated Silylhydroxylamines with Fluorosilanes

1981 ◽  
Vol 36 (11) ◽  
pp. 1356-1360 ◽  
Author(s):  
Dieter Bentmann ◽  
Uwe Klingebiel
Keyword(s):  
Intramolecular Rearrangement ◽  
Analogous Reaction ◽  
Rearrangement Reactions

Abstract Halogenosilanes, with the exception of CH3SiF3 and SiF4, react with lithiated bis-(trimethylsilyl)hydroxylamine in ether to yield substituted hydroxylamines, and LiF. In the analogous reaction with trifluoromethylsilane and tetrafluorosilane the products undergo an intramolecular rearrangement to form silylaminosiloxanes.

Ab Initio SCF and DFT Studies on Solvent Effects on Intramolecular Rearrangement Reactions

2001 ◽  
Vol 105 (17) ◽  
pp. 4272-4283 ◽  
Author(s):  
Pratim K. Chattaraj ◽  
Patricia Pérez ◽  
Jenny Zevallos ◽  
Alejandro Toro-Labbé
Keyword(s):  
Ab Initio ◽  
Solvent Effects ◽  
Intramolecular Rearrangement ◽  
Dft Studies ◽  
Rearrangement Reactions
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