The Hammond Postulate and the Principle of Maximum Hardness in Some Intramolecular Rearrangement Reactions

1999 ◽  
Vol 103 (44) ◽  
pp. 8847-8852 ◽  
Author(s):  
Miquel Solà ◽  
Alejandro Toro-Labbé
Keyword(s):  
Intramolecular Rearrangement ◽  
Maximum Hardness ◽  
Rearrangement Reactions ◽  
Principle Of Maximum

Principle of maximum hardness: an accurate ab initio study

1993 ◽  
Vol 97 (17) ◽  
pp. 4404-4406 ◽  
Author(s):  
Sourav Pal ◽  
Nayana Vaval ◽  
Ramkinkar Roy
Keyword(s):  
Ab Initio ◽  
Ab Initio Study ◽  
Maximum Hardness ◽  
Principle Of Maximum

Umlagerungsreaktionen von lithiierten Silylhydroxylaminen mit Fluorsilanen / Rearrangement Reactions of Lithiated Silylhydroxylamines with Fluorosilanes

1981 ◽  
Vol 36 (11) ◽  
pp. 1356-1360 ◽  
Author(s):  
Dieter Bentmann ◽  
Uwe Klingebiel
Keyword(s):  
Intramolecular Rearrangement ◽  
Analogous Reaction ◽  
Rearrangement Reactions

Abstract Halogenosilanes, with the exception of CH3SiF3 and SiF4, react with lithiated bis-(trimethylsilyl)hydroxylamine in ether to yield substituted hydroxylamines, and LiF. In the analogous reaction with trifluoromethylsilane and tetrafluorosilane the products undergo an intramolecular rearrangement to form silylaminosiloxanes.

Local hardness equalization and the principle of maximum hardness

2013 ◽  
Vol 138 (21) ◽  
pp. 214103 ◽  
Author(s):  
José L. Gázquez ◽  
Alberto Vela ◽  
Pratim K. Chattaraj
Keyword(s):  
Maximum Hardness ◽  
Local Hardness ◽  
Principle Of Maximum
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