Carbon monoxide and methyl isocyanide cmplexes of methylatobis(dimethylglyoximato)cobalt(III)

Theodore Lawrence Brown; Albert W. Herlinger

doi:10.1021/ja00736a042

Carbon monoxide and methyl isocyanide cmplexes of methylatobis(dimethylglyoximato)cobalt(III)

Journal of the American Chemical Society ◽

10.1021/ja00736a042 ◽

1971 ◽

Vol 93 (7) ◽

pp. 1790-1791 ◽

Cited By ~ 14

Author(s):

Theodore Lawrence Brown ◽

Albert W. Herlinger

Keyword(s):

Carbon Monoxide ◽

Methyl Isocyanide

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ChemInform Abstract: CARBON MONOXIDE, CARBON MONOSULFIDE, MOLECULAR NITROGEN, PHOSPHORUS TRIFLUORIDE, AND METHYL ISOCYANIDE AS Σ DONORS AND Π ACCEPTORS. A THEORETICAL STUDY BY THE HARTREE-FOCK-SLATER TRANSITION-STATE METHOD

Chemischer Informationsdienst ◽

10.1002/chin.197942085 ◽

1979 ◽

Vol 10 (42) ◽

Author(s):

T. ZIEGLER ◽

A. RAUK

Keyword(s):

Carbon Monoxide ◽

Transition State ◽

Theoretical Study ◽

Molecular Nitrogen ◽

Hartree Fock ◽

Methyl Isocyanide ◽

State Method ◽

Carbon Monosulfide ◽

Nitrogen Phosphorus

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Formation of highly functionalized metal-bound acetylenes by reductive coupling of carbon monoxide and methyl isocyanide ligands

Journal of the American Chemical Society ◽

10.1021/ja00037a019 ◽

1992 ◽

Vol 114 (11) ◽

pp. 4166-4174 ◽

Cited By ~ 25

Author(s):

Edmund M. Carnahan ◽

Stephen J. Lippard

Keyword(s):

Carbon Monoxide ◽

Reductive Coupling ◽

Isocyanide Ligands ◽

Methyl Isocyanide

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ChemInform Abstract: COMPETITIVE REACTIONS OF COORDINATED CARBON MONOXIDE AND METHYL ISOCYANIDE WITH AMINES

Chemischer Informationsdienst ◽

10.1002/chin.197427371 ◽

1974 ◽

Vol 5 (27) ◽

pp. no-no

Author(s):

R. J. ANGELICI ◽

P. A. CHRISTIAN ◽

B. D. DOMBEK ◽

G. A. PFEFFER

Keyword(s):

Carbon Monoxide ◽

Competitive Reactions ◽

Methyl Isocyanide

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Carbon dioxide induced metathesis of CN and CO triple bonds of methyl isocyanide and carbon monoxide

Journal of the Chemical Society Chemical Communications ◽

10.1039/c39870001412 ◽

1987 ◽

pp. 1412-1413 ◽

Cited By ~ 14

Author(s):

Dru L. DeLaet ◽

Phillip E. Fanwick ◽

Clifford P. Kubiak

Keyword(s):

Carbon Dioxide ◽

Carbon Monoxide ◽

Triple Bonds ◽

Methyl Isocyanide

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Addition of carbon monoxide and methyl isocyanide to methyl palladium A-frame complexes and some reactions of the product acyl complexes

Organometallics ◽

10.1021/om00066a011 ◽

1982 ◽

Vol 1 (6) ◽

pp. 824-829 ◽

Cited By ~ 11

Author(s):

Chung Li Lee ◽

Catherine T. Hunt ◽

Alan L. Balch

Keyword(s):

Carbon Monoxide ◽

Acyl Complexes ◽

Methyl Isocyanide

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The migratory insertion of carbon monoxide and methyl isocyanide into zirconium?carbon and titanium?carbon bonds anchored to a calix[4]arene moiety: a dynamical density functional study

Theoretical Chemistry Accounts ◽

10.1007/s00214-003-0472-0 ◽

2003 ◽

Vol 110 (3) ◽

pp. 196-204 ◽

Cited By ~ 7

Author(s):

Filippo De Angelis ◽

Simona Fantacci ◽

Antonio Sgamellotti ◽

Nazzareno Re

Keyword(s):

Carbon Monoxide ◽

Density Functional ◽

Functional Study ◽

Density Functional Study ◽

Migratory Insertion ◽

Carbon Bonds ◽

Methyl Isocyanide

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Charge donation to and dearomatization of benzene attending complexation: DFT estimates of binding energies of TpMXO(L) with benzene, for Tp = hydridotris(pyrazolyl) borate, MXO = MoNO, ReCO, and WNO, and L = ammonia,N-methylimidazole, pyridine, phosphine, methyl isocyanide, and carbon monoxide

Journal of Computational Chemistry ◽

10.1002/jcc.20155 ◽

2004 ◽

Vol 26 (2) ◽

pp. 194-200 ◽

Cited By ~ 5

Author(s):

W. Dean Harman ◽

Carl Trindle

Keyword(s):

Carbon Monoxide ◽

Binding Energies ◽

Methyl Isocyanide

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ChemInform Abstract: Reductive Coupling of Carbon Monoxide with Methyl Isocyanide in a Seven-Coordinate Niobium Complex.

ChemInform ◽

10.1002/chin.199030248 ◽

1990 ◽

Vol 21 (30) ◽

Author(s):

E. M. CARNAHAN ◽

S. J. LIPPARD

Keyword(s):

Carbon Monoxide ◽

Reductive Coupling ◽

Methyl Isocyanide

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Double-mixing kinetic studies of the reactions of methyl isocyanide and carbon monoxide with diliganded intermediates of hemoglobin: .alpha.2CO.beta.2 and .alpha.2.beta.2CO

Biochemistry ◽

10.1021/bi00495a014 ◽

1990 ◽

Vol 29 (43) ◽

pp. 10106-10113 ◽

Cited By ~ 9

Author(s):

Marjaneh Berjis ◽

Debkumar Bandyopadhyay ◽

Vijay S. Sharma

Keyword(s):

Carbon Monoxide ◽

Kinetic Studies ◽

Methyl Isocyanide

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The kinetics of the reduction of isocyanides, acetylenes and the cyanide ion by nitrogenase preparation from Azotobacter chroococcum and the effects of inhibitors

Biochemical Journal ◽

10.1042/bj1070001 ◽

1968 ◽

Vol 107 (1) ◽

pp. 1-6 ◽

Cited By ~ 33

Author(s):

M Kelly

Keyword(s):

Carbon Monoxide ◽

Nitrogen Fixation ◽

Azotobacter Chroococcum ◽

Nitrogen Fixing ◽

Cyanide Ion ◽

Nitrogen Fixing Bacteria ◽

Methyl Isocyanide ◽

Kinetics Of

1. Nitrogen-fixing preparations from Azotobacter chroococcum reduced substrates with the following Km values: methyl isocyanide, 1·8×10−4m; ethyl isocyanide, 2·5×10−2m; cyanide ion, 1·4×10−3m; acetylene, 1·2×10−4m. 2. Nitrogen, carbon monoxide or hydrogen competitively inhibited isocyanide reduction with the following Ki values: hydrogen, 1·3×10−3m; carbon monoxide, 6·8×10−6m; nitrogen, 4·3×10−4m. 3. Living nitrogen-fixing bacteria, and isolated clover nodules, formed methane from methyl isocyanide. 4. These results are discussed in relation to other work and possible mechanisms of nitrogen fixation.

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