Enzymatic monooxygenation of halogen atoms: cytochrome P-450 catalyzed oxidation of iodobenzene by iodosobenzene

1980 ◽  
Vol 102 (25) ◽  
pp. 7615-7616 ◽  
Author(s):  
Leo T. Burka ◽  
Alice Thorsen ◽  
F. Peter Guengerich
Keyword(s):  
Halogen Atoms ◽  
Cytochrome P 450 ◽  
Catalyzed Oxidation

scholarly journals Manganese and iron tetraphenylporphyrin-catalyzed oxidation of a cardanol derivative (hydrogenated tert-butylcardanol)

2002 ◽  
Vol 06 (01) ◽  
pp. 12-16 ◽  
Author(s):  
Pietro Tagliatesta ◽  
Claudia Crestini ◽  
Raffaele Saladino ◽  
Veronica Neri ◽  
Paolino Filippone ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Oxygen Atom ◽  
Reaction Products ◽  
Catalyst Structure ◽  
Halogen Atoms ◽  
Catalyzed Oxidation

Manganese and iron 2,6-disubstituted meso-tetraphenylporphyrins, bearing halogen atoms on the β-positions, have been used as catalysts for the oxidation of a cardanol derivative (hydrogenated tert-butylcardanol), using iodosilbenzene or hydrogen peroxide as oxygen atom donors. The reaction products can be correlated to the catalyst structure and to the nature of the oxidants.

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