Bond fixation in annulenes. 9. Equalization of ring inversion and bond shifting energetics in 1,2,3,4-tetramethylcyclooctatetraene. Asymmetric synthesis direct resolution, and absolute configuration of the optically active hydrocarbon

1980 ◽  
Vol 102 (15) ◽  
pp. 5026-5032 ◽  
Author(s):  
Leo A. Paquette ◽  
John M. Gardlik ◽  
Larry K. Johnson ◽  
Kevin J. McCullough
2015 ◽  
Vol 51 (2) ◽  
pp. 380-383 ◽  
Author(s):  
Masahiro Egi ◽  
Kaori Shimizu ◽  
Marin Kamiya ◽  
Yuya Ota ◽  
Shuji Akai

An asymmetric synthesis of highly substituted indenes has been developed via the central–axial–central chirality transfer from optically active propargyl alcohols.


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